Ru(II) xantphos complex as an efficient catalyst in transfer hydrogenation of carbonyl compounds

被引：15

作者：

Kharat, Ali Nemati ^{[1
]}

Bakhoda, Abolghasem ^{[1
]}

Jahromi, Bahareh Tamaddoni ^{[1
]}

机构：

[1] Univ Tehran, Univ Coll Sci, Sch Chem, Tehran, Iran

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 07期

关键词：

Ruthenium complex; Xantphos; Transfer hydrogenation; X-ray crystallography; Hydrogen bonding; C-H center dot center dot center dot pi interaction; BITE ANGLE; BONDING INTERACTIONS; RUTHENIUM; DIPHOSPHINES; CHLORIDES; LIGANDS;

D O I：

10.1016/j.inoche.2011.04.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the transfer hydrogenation of aromatic/aliphatic carbonyl compounds using iso-propanol-potassium hydroxide mixture as hydrogen donor, a mixed ligand Ru(II) complex, prepared from xantphos ligand and RuCl2(dmso)(4), was examined. Besides, the solid state structure of the Ru(II) complex was determined using X-ray single crystallography. The catalytic reactivity of the complex was remarkable (up to 99%) and the catalyst showed more efficiency in the reduction of ketones than aldehydes. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1161 / 1164

页数：4

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