Dependence of spectral shape of total bremsstrahlung spectra i.e. the sum of ordinary bremsstrahlung (OB) and polarization bremsstrahlung (PB), on the atomic number (Z) of target materials (Al, Ti, Sn and Pb), produced by continuous beta particles of Sr-90 and Tl-204, has been investigated in the photon energy region of 5-30 key. It has been found that the spectral shape of total bremsstrahlung spectra, in terms of S (k, Z) i.e. the number of photons of energy k per m(o)c(2) per beta disintegration, is not linearly dependent on the atomic number (Z) of the target material and rather it is proportional to Z(n). At lower photon energies, the index values 'n' of Z-dependence are much higher than unity, which is due to the larger contribution of PB into OB. The decrease in 'n' values with increase of photon energy is due to the decrease in contribution of PB into OB. It is clear that the index 'n' values obtained from the modified Elwert factor (relativistic) Bethe-Heitler theory, which include the contribution PB into OB, are in agreement with the experimentally measured results using X-PIPS Si(Li) detector. Hence the contribution of PB into the formation of a spectral shape of total bremsstrahlung spectra plays a vital role. (C) 2011 Elsevier B.V. All rights reserved.