Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst

被引：4
|
作者：
Cai, Yueqin [1 ]
Liu, Ye [1 ]
Gao, Guohua [1 ]
机构：
[1] E China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
来源：
MONATSHEFTE FUR CHEMIE | 2007年 / 138卷 / 11期
关键词：
catalysts; Baylis-Hillman reaction; aldehydes; acrylates; homogeneous catalysis;
D O I：
10.1007/s00706-007-0693-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo [2.2.2] octane chloride based on 1,4-diazabicyclo[2.2.2] octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.
引用
收藏
页码：1163 / 1166
页数：4
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