Excitonic effects of metallic single-walled carbon nanotubes are measured with temperature-dependent resonant Raman spectroscopy. By changing the temperature in the range of 300-870 K, we observe variations in the optical transition energy E(ii) as well as in the maximum Raman intensity. We find both dependences to be different for semiconducting and metallic single-walled carbon nanotubes. We suggest an interpretation in terms of excitons dissociated into free electron-hole pairs at temperatures related to the exciton binding energy. We furthermore discuss how the oscillator strength is influenced by temperature.
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Univ Hong Kong, Dept Phys, Hong Kong, Peoples R ChinaUniv Hong Kong, Dept Phys, Hong Kong, Peoples R China
Zeng, Hualing
Zhao, Hongbo
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Univ Hong Kong, Dept Phys, Hong Kong, Peoples R China
Univ Hong Kong, Ctr Theoret & Computat Phys, Hong Kong, Peoples R ChinaUniv Hong Kong, Dept Phys, Hong Kong, Peoples R China
Zhao, Hongbo
Zhang, Fu-Chun
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Univ Hong Kong, Dept Phys, Hong Kong, Peoples R China
Univ Hong Kong, Ctr Theoret & Computat Phys, Hong Kong, Peoples R ChinaUniv Hong Kong, Dept Phys, Hong Kong, Peoples R China
Zhang, Fu-Chun
Cui, Xiaodong
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Univ Hong Kong, Dept Phys, Hong Kong, Peoples R China
Univ Hong Kong, CAS Joint Lab New Mat, Hong Kong, Peoples R ChinaUniv Hong Kong, Dept Phys, Hong Kong, Peoples R China