Facile Synthesis of Sulfonyl Amidines and β-Amino Sulfonyl Enamines under Transition-Metal-Free Conditions

被引：32

作者：

Gao, Tingting ^{[1
]}

Zhao, Mingming ^{[1
]}

Meng, Xu ^{[1
]}

Li, Chuanbin ^{[1
]}

Chen, Baohua ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China

来源：

SYNLETT | 2011年 / 09期

基金：

美国国家科学基金会;

关键词：

enamine; azide; amidine; catalyst-free; C-H BONDS; COPPER-CATALYZED AMIDATION; ONE-POT SYNTHESIS; 1,3-DICARBONYL COMPOUNDS; HYDROGEN-PEROXIDE; TERTIARY-AMINES; NITROGEN ATOM; ACTIVATION; FUNCTIONALIZATION; CYCLIZATION;

D O I：

10.1055/s-0030-1260548

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of enamine and azide resulted in the formation of either sulfonyl amidine or beta-amino sulfonyl enamine derivative in moderate to good yields. The reaction could proceed under catalyst-free conditions.

引用

页码：1281 / 1284

页数：4

共 50 条

[21] Facile, regioselective oxidative selenocyanation of N-aryl enaminones under transition-metal-free conditions
Sorabad, Ganesh Shivayogappa
Maddani, Mahagundappa Rachappa
NEW JOURNAL OF CHEMISTRY, 2020, 44 (06) : 2222 - 2227
[22] Three-Component Synthesis of Dibenzoxazepinamines and Dibenzothiazepinamines under Transition-Metal-Free Conditions
Fang, Fang
Jiang, Shuxin
Lei, Hanwen
Chen, Shanping
Deng, Guo-Jun
JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (21): : 15658 - 15664
[23] Visible-Light-Mediated ipso -Carbosulfonylation of Alkynes: Synthesis of 3-Sulfonylspiro[4,5]trienones from Propiolamides and Sulfonyl Chlorides under Transition-Metal-Free Conditions
Liu, Yu
Wang, Qiao-Lin
Xiong, Bi-Quan
Zhang, Pan-Liang
Yang, Chang-An
Gong, Yan-Xia
Liao, Jing
Zhou, Quan
SYNLETT, 2018, 29 (18) : 2396 - 2403
[24] Transition-metal-free hydroamination/defluorination/cyclization of perfluoroalkyl alkynes with amidines
Sun, Li-Wen
Yu, Zi-Lun
Luo, Xin-Long
Ma, Mengtao
Shen, Zhi-Liang
Chu, Xue-Qiang
ORGANIC CHEMISTRY FRONTIERS, 2021, 9 (01): : 109 - 116
[25] Alumina as an Efficient Catalyst for the Preparation of Sulfonyl Hydrazides and Sulfonyl Semicarbazides Under Solvent-free Conditions
Javad Safaei-Ghomi
Aboalfazl Abbaszadeh-Nooshabady
复旦学报(自然科学版), 2005, (05) : 269 - 270
[26] A green and novel method for synthesis of β-sulfonyl esters under solvent-free conditions
Imanzadeh, Gholamhassan
Rezaei, Havva
Asgharzadeh, Roghayyeh
Soltanzadeh, Zahra
JOURNAL OF SULFUR CHEMISTRY, 2021, 42 (04) : 359 - 368
[27] Synthesis of Multiarmed Thienylene-Tetrafluorophenylene Alternating Copolymers under Transition-Metal-Free Conditions
Sanji, Takanobu
Kakinuma, Junko
Iyoda, Tomokazu
MACROMOLECULES, 2016, 49 (18) : 6761 - 6767
[28] Facile synthesis of 4-quinolone derivatives via one-pot cascade reaction under transition-metal-free conditions
Huang, Chao
Guo, Jia-Hui
Fu, Huang-Mei
Yuan, Ming-Long
Yang, Li-Juan
TETRAHEDRON LETTERS, 2015, 56 (24) : 3777 - 3781
[29] C–F bond activation under transition-metal-free conditions
HanJun Ai
Xingxing Ma
Qiuling Song
XiaoFeng Wu
Science China(Chemistry), 2021, (10) : 1630 - 1659
[30] Transition-Metal-Free Dehydrosilylative Difluoroamidation of Tetrahydroisoquinolines under Mild Conditions
Chen, Qiao
Zhou, Jiawei
Wang, Yanan
Wang, Chao
Liu, Xihong
Xu, Zhaoqing
Lin, Li
Wang, Rui
ORGANIC LETTERS, 2015, 17 (17) : 4212 - 4215

← 1 2 3 4 5 →