Pd-Ru nanocatalysts derived from a Pd-induced aerogel for dramatic boosting of hydrogen release

被引：18
|
作者：
Yang, Xiaojiao [1 ]
Wei, Jianyu [1 ,2 ]
Wang, Qi [2 ]
Shuai, Maobing [1 ]
Yue, Guozong [1 ]
Li, Peilong [1 ]
Huang, Deshun [1 ]
Astruc, Didier [2 ]
Zhao, Pengxiang [1 ]
机构：
[1] China Acad Engn Phys, Inst Mat, 9 Huafengxincun, Jiangyou City 621908, Sichuan, Peoples R China
[2] Univ Bordeaux, ISM, UMR CNRS 5255, F-33405 Talence, France
来源：
NANOSCALE | 2020年 / 12卷 / 04期
基金：
中国国家自然科学基金;
关键词：
AMMONIA-BORANE; HYDROLYTIC DEHYDROGENATION; HIGH-EFFICIENCY; NANOPARTICLES; CATALYST; EVOLUTION;
D O I：
10.1039/c9nr09307a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alloyed bimetallic Pd-Ru nanocatalysts prepared by in situ reduction of a mixture of a Ru(III) source and a Pd(II)@alkyne-PVA aerogel and characterized by TEM and XPS exhibit very highly catalytic activity towards hydrogen release from ammonia borane hydrolysis with a TOF value of 578.2 mol(H2) mol(cat)(-1) min(-1).
引用
收藏
页码：2345 / 2349
页数：5
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