Synthetic approach to new alpha-aminophosphonates derived from six-membered, sulfur-containing heterocyclic imines

被引：11

作者：

Groger, H ^{[1
]}

Manikowski, J ^{[1
]}

Martens, J ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,D-2900 OLDENBURG,GERMANY

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1996年 / 116卷

关键词：

alpha-aminophosphonates; 1,3-thiazinan-4-yl-phosphonates 3,4-dihydro-2H-1,4-benzothiazine-3-phosphonates;

D O I：

10.1080/10426509608040475

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dialkyl phosphite adds to the C=N bond in 2H-1,3-thiazines 4 to give alpha-aminophosphonic acid esters 6. Starting from 2H-1,4-benzothiazines 5, the corresponding phosphonic acid esters 7 were obtained. For the first time C2-chiral 2H-1,3-thiazines 4a and 4b were used to investigate the diastereoselectivity of the addition reaction of dialkyl phosphite to those imine compounds.

引用

页码：123 / 132

页数：10

共 32 条

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Fuchita, Y
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