Silver sequestration of halides for the activation of Pd(OAc)2 catalyzed Mizoroki-Heck reaction of 1,1 and 1,2-Disubstituted alkenes

被引：7
|
作者：
Bangar, Pronnoy G. [1 ,2 ]
Jawalkar, Priyanka R. [3 ]
Dumbre, Swapnil R. [1 ]
Patil, Dharmaraj J. [1 ]
Iyer, Suresh [1 ,2 ]
机构：
[1] Natl Chem Lab, Div Organ Chem, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India
[2] Acad Sci & Innovat Res, New Delhi 110025, India
[3] Sai Life Sci Ltd, Dept Med Chem, Int Biotech Pk,Phase 2, Pune 411057, Maharashtra, India
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2018年 / 32卷 / 03期
关键词：
1,1-disubstituted alkenes; 1,2-disubstituted alkenes; AgBF4; AgOAc; Mizoroki-Heck reaction; CROSS-COUPLING REACTIONS; TRISUBSTITUTED ALKENES; TETRASUBSTITUTED ALKENES; DISUBSTITUTED ALKENES; PALLADIUM CATALYST; MCMURRY REACTION; ARYL CHLORIDES; IONIC LIQUIDS; OLEFINS; ARYLATION;
D O I：
10.1002/aoc.4159
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A ligand free catalytic system consisting of Pd(OAc)(2) (cat) and stoichiometric quantities of silver salts, AgOAc or AgBF4, exhibit high efficiency in the Mizoroki-Heck arylation, transforming aryl iodides and 1,1 as well as 1,2 disubstituted alkenes into 1,1,2 - trisubstituted aryl alkenes in excellent yields in very short reaction times.
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页数：6
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