Sensitivity of SnO2 non-ohmic behavior to the sintering process and to the addition of La2O3

被引:28
|
作者
Oliveira, MM
Bueno, PR
Cassia-Santos, MR
Longo, E
Varela, JA
机构
[1] Univ Fed Sao Carlos, Dept Quim, CMDMC, LIEC, BR-13560 Sao Carlos, SP, Brazil
[2] UNESP, Inst Quim, BR-14801970 Araraquara, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
electrical properties; La2O3; sintering; SnO2; varistors;
D O I
10.1016/S0955-2219(00)00329-0
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The work reported here consisted of a study of the sensitivity of the nonlinear electrical properties of dense SnO2. CoO ceramic systems to low concentrations of La2O3, sintering temperature and cooling rates. The nonlinear electrical properties of these systems were found to increase with decreasing cooling rates, a behavior attributed to the CoO solid state reactions at temperatures below 1000 degreesC. Post-annealing treatment in N-2-rich atmospheres strongly decreases the non-ohmic behavior of SnO2. CoO ceramic systems. However, this behavior may be restored through thermal treatment in an O-2-rich atmosphere. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1179 / 1185
页数:7
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