Study of Pu sorption behavior in natural clay

被引：3

作者：

Lujaniene, G. ^{[1
]}

Stamberg, K. ^{[2
]}

Pakstas, V. ^{[1
]}

Juskenas, R. ^{[1
]}

Kulakauskaite, I. ^{[1
]}

Semcuk, S. ^{[1
]}

Mazeika, K. ^{[1
]}

Vopalka, D. ^{[2
]}

机构：

[1] SRI Ctr Phys Sci & Technol, LT-02300 Vilnius, Lithuania

[2] Czech Tech Univ, Dept Nucl Chem, Prague, Czech Republic

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2015年 / 304卷 / 01期

关键词：

Pu(V); Pu(IV); Oxidation state distribution; Natural clay; Sorption kinetics; Sequential extraction; ACTINIDE SPECIATION; OXIDATION-STATES; REDUCTION; AM; ADSORPTION; AMERICIUM; PLUTONIUM; KINETICS; PU(V); CS;

D O I：

10.1007/s10967-014-3585-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Kinetics of Pu(V) sorption on clays was studied under conditions similar to those expected at the waste repository. Batch sorption, sequential extraction (SE), oxidation state analysis and modeling were applied to study sorption mechanisms of Pu. The composition of clay coatings and their transformation were investigated using the Mossbauer spectroscopy and X-ray diffraction. In spite of the Pu(V) fast reduction its bonding to the clay was found to be different as compared to the experiments with Pu(IV). The largest portion of Pu was associated with exchangeable and carbonate fractions indicating its possible higher mobility in the environment.

引用

页码：53 / 59

页数：7

共 50 条

[31] Heavy metal interactions with phosphatic clay: Sorption and desorption behavior
Singh, SP
Ma, LQ
Harris, WG
JOURNAL OF ENVIRONMENTAL QUALITY, 2001, 30 (06) : 1961 - 1968
[32] SORPTION BEHAVIOR OF CESIUM AND STRONTIUM IONS ON MIXTURES OF CLAY SORBENTS
YANAGI, T
WATANABE, M
YAMAMOTO, K
JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY, 1989, 26 (09) : 861 - 864
[33] SORPTION BEHAVIOR OF CESIUM, STRONTIUM AND AMERICIUM IONS ON CLAY MATERIALS
KONISHI, M
YAMAMOTO, K
YANAGI, T
OKAJIMA, Y
JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY, 1988, 25 (12) : 929 - 933
[34] Critical clay content in defining sorption behavior of pesticides in soil
Huang, Xiao
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
[35] Sorption and desorption behavior of tributyltin with natural sediments
Burton, ED
Phillips, IR
Hawker, DW
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (24) : 6694 - 6700
[36] Cadmium sorption behavior of natural and synthetic zeolites
Singh, B
Alloway, BJ
Bochereau, FJM
COMMUNICATIONS IN SOIL SCIENCE AND PLANT ANALYSIS, 2000, 31 (17-18) : 2775 - 2786
[37] The Water Vapor Sorption Behavior of Natural Fibers
Hill, Callum A. S.
Norton, Andrew
Newman, Gary
JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 112 (03) : 1524 - 1537
[38] Sorption of cationic dyes from aqueous solution onto natural clay. Equilibrium and kinetic study
Caliman, Florentina Anea
Gavrilescu, Maria
ENVIRONMENTAL ENGINEERING AND MANAGEMENT JOURNAL, 2008, 7 (03): : 301 - 308
[39] Radiocaesium sorption on natural glauconite sands is unexpectedly as strong as on Boom Clay
Bruneel, Y.
Van Laer, L.
Brassinnes, S.
Smolders, E.
SCIENCE OF THE TOTAL ENVIRONMENT, 2020, 720 (720)
[40] Sorption properties of natural aluminosilicates (clay, loam, sandy loam, zeolite)
Evtyukhov, SA
Berezyuk, VG
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2003, 76 (09) : 1414 - 1417

← 1 2 3 4 5 →