INTRAMOLECULAR AND INTERMOLECULAR HYDROGEN BONDS IN AMINOPHENOLS

被引：6

作者：

Belkov, M. V. ^{[1
]}

Ksendzova, G. A. ^{[2
]}

Polozov, G. I. ^{[2
]}

Skornyakov, I. V. ^{[1
]}

Sorokin, V. L. ^{[2
]}

Tolstorozhev, G. B. ^{[1
]}

Shadyro, O. I. ^{[2
]}

机构：

[1] Natl Acad Sci Belarus, BI Stepanov Inst Phys, Minsk 220072, BELARUS

[2] Belarusian State Univ, Minsk, BELARUS

来源：

JOURNAL OF APPLIED SPECTROSCOPY | 2010年 / 77卷 / 04期

关键词：

aminophenol; IR spectrum; intramolecular hydrogen bond; intermolecular hydrogen bond; DERIVATIVES;

D O I：

10.1007/s10812-010-9359-8

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

IR-Fourier spectroscopy methods are adopted to study intramolecular and intermolecular hydrogen bonds that form in CCl4 solutions of aminophenol derivatives and in a solid phase of these compounds pressed in KBr. If a hydroxyl group is present in the molecule in the ortho-position to an amino group, then intramolecular interactions between OH and NH groups will take place in aminophenol solutions. Intramolecular O-H center dot center dot center dot O=S=O and N-H center dot center dot center dot O=S=O hydrogen bonds are found in solutions of compounds containing a sulfonamide fragment. Additional acylation of the amino group causes an intramolecular O-H center dot center dot center dot O=C hydrogen bond to form in solutions. Functional groups OH, NH, SO2, and C=O interact with one another in various ways in the solid phase to form intermolecular hydrogen bonds in aminophenols.

引用

页码：496 / 501

页数：6

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