Synthesis and coordination chemistry of PEt(C6H4-4-C6F13)2.: Crystal structure of cis-[PtCl2{Pet(C6H4-4C6F13)2}2]

被引：19

作者：

Fawcett, J ^{[1
]}

Hope, EG ^{[1
]}

Russell, DR ^{[1
]}

Stuart, AM ^{[1
]}

Wood, DRW ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

POLYHEDRON | 2001年 / 20卷 / 3-4期

关键词：

fluorous biphase; phosphine; platinum group metals; single crystal X-ray study;

D O I：

10.1016/S0277-5387(00)00609-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and coordination chemistry of the PEt(C6H4-4-C6F13)(2) ligand has been investigated including the single crystal X-ray structural characterisation of cis-[PtCl2{PEt(C6H4-C6F13)(2)}(2)]. The spectroscopic data for [RhCl2(eta (5)-C5Me5)L], trans[MCl(CO)L-2] (M = Rh, Ir) and cis-[PtCl2L2] {L = PEt(C6H4-4-C6F13)(2)} indicate that the ethyl group is unable to meliorate against the electron withdrawing effects of the perfluoroalkyl groups. The crystal structure illustrates that the perfluoroalkyl groups have little influence on the platinum coordination environment but that the solid state packing is dominated by short F . . .F interactions. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：321 / 326

页数：6

共 50 条

[41] Crystal structure of Co(II)/Zn(II) coordination polymers supported by 1,3-bis(4-pyridyl)propane, {[Co(ClO4)2(C13H14N2)2]•2C6H6}n and {[Zn(ClO4)2(C13H14N2)2]•2C6H6}n
Bujici, TM
Wang, XT
Li, SJ
Zheng, C
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2003, 218 (01): : 148 - 148
[42] Reaction of H atoms with solid C2H4 and C2H6 at 13 K
Hiraoka, K
Yamamoto, K
Kihara, Y
Takayama, T
Sato, T
ASTROPHYSICAL JOURNAL, 1999, 514 (01): : 524 - 528
[43] MECHANISMS OF ETCHING AND POLYMERIZATION IN RADIOFREQUENCY DISCHARGES OF CF4-H2,CF4-C2F4,C2F6-H2,C3F8-H2
DAGOSTINO, R
CRAMAROSSA, F
COLAPRICO, V
DETTOLE, R
JOURNAL OF APPLIED PHYSICS, 1983, 54 (03) : 1284 - 1288
[44] BIS-ORTHO-METALATED PALLADIUM COMPLEXES - NEW EXAMPLES AND REACTIVITY - THE X-RAY CRYSTAL-STRUCTURE OF CIS-(2-C6H5N=NC6H4)2PD AND CIS-(2-C6H5N=NC6H4)(2-ME2NCH2C6H4)PD
JANECKI, T
JEFFREYS, JAD
PAUSON, PL
PIETRZYKOWSKI, A
MCCULLOUGH, KJ
ORGANOMETALLICS, 1987, 6 (07) : 1553 - 1560
[45] Synthesis and reactivity of [N(C6H4Br)3][B(C6F5)4]:: the X-ray crystal structure of [Fe(C5H5)2][B(C6F5)4]
O'Connor, AR
Nataro, C
Golen, JA
Rheingold, AL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (14) : 2411 - 2414
[46] THE INFLUENCE OF THE CATION ON THE STRUCTURE OF THE ANION [SI(O2C6H4)2F]- - THE STRUCTURE OF [K(18-KRONE-6)][SI(O2C6H4)2F]
DETTLAFFWEGLIKOWSKA, U
HEYHAWKINS, E
VONSCHNERING, HG
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (05): : 609 - 614
[47] VIBRATIONAL DEPENDENCE OF ELECTRONIC NONRADIATIVE PROCESSES IN THE B-STATE OF C6F6+ AND 1,2,4,5-C6F4H2+
WINKOUN, D
CHAPOULARD, D
DUJARDIN, G
LEACH, S
CANADIAN JOURNAL OF PHYSICS, 1984, 62 (12) : 1361 - 1368
[48] Crystal structure of acridinium dichloro(pyridine-2-carboxylato-κ2N,O)platinate(II), [C13H10N][PtCl2(C6H4NO2)]
Ha, Kwang
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (03): : 325 - 326
[49] Hydrothermal synthesis and crystal structure of a new phosphonate:: {[Cu(1,10-phen)]2(H2O3PCH2C6H4C6H4CH2PO3H)2- (HO3PCH2C6H4C6H4CH2PO3H)}n
Fu, RB
Wu, XT
Hu, SM
Wang, LS
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (10) : 1107 - 1110
[50] MOLECULAR + CRYSTAL STRUCTURES OF B4H6C2H2 + B4H6C2(CH3)2
BOER, FP
STREIB, WE
LIPSCOMB, WN
INORGANIC CHEMISTRY, 1964, 3 (12) : 1666 - &

← 1 2 3 4 5 →