Optical properties of new chalcogenide glasses from the GeSe2-Sb2Se3-PbSe system

被引:20
|
作者
Parvanov, Svedin [1 ]
Vassilev, Venceslav [2 ]
Tomova, Katerina [2 ]
机构
[1] Univ Chem Technol & Met, Cent Res Lab, Sofia 1756, Bulgaria
[2] Univ Chem Technol & Met, Dept Semicond, Sofia 1756, Bulgaria
关键词
chalcogenide glasses; optical materials and properties; semiconductors; thin films;
D O I
10.1016/j.matlet.2007.11.029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Optical properties of thin films in the GeSe2-Sb2Se3-PbSe system are studied as a function of the PbSe content and at different ratio GeSe2/Sb2Se3. Transmission spectra of thin films are investigated. From the above spectra the absorption coefficient CL for different PbSe content are derived. The increase of the absorption coefficient alpha is attributed to the increase of the current carriers density in the valence band. Optical band gap of the samples is determined using Tauc's procedure. A correlation between the optical band gap and the composition of these chalcogenide samples could be seen. This might result from the increasingly stronger metal character of the bond that leads to the formation of a complicated band gap structure. (c) 2008 Elsevier B.V. All fights reserved.
引用
收藏
页码:2021 / 2024
页数:4
相关论文
共 50 条
  • [41] Thermal Properties, Microstructure, and Conductivity of New Glasses Based on the GeSe2-Ga2Se3-AgI System
    Tang, Gao
    Liu, Cunming
    Luo, Lan
    Chen, Wei
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (12) : 4171 - 4174
  • [42] A Zn(II) ion-selective electrode based on chalcogenide As2Se3–Sb2Se3–ZnSe and GeSe2–ZnSe–ZnTe glasses
    S.V. Boycheva
    V.S. Vassilev
    Z.G. Ivanova
    Journal of Applied Electrochemistry, 2002, 32 : 281 - 285
  • [43] New chalcogenide glasses in the Ag2Te-AS2Se3-CdTe system
    Vassilev, V.
    Karadashka, I.
    Parvanov, S.
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (07) : 1835 - 1840
  • [44] Effect of CsCl content on crystallization characteristics and properties of infrared transmitting of GeSe2-Sb2Se3 glasses
    Lan, Jianhua
    Xu, Tiefeng
    Nie, Qiuhua
    Dai, Shixun
    Zhao, Jun
    Shen, Xiang
    Zhang, Xianghua
    Kuei Suan Jen Hsueh Pao/ Journal of the Chinese Ceramic Society, 2009, 37 (04): : 568 - 573
  • [45] Laser Desorption Ionisation Time-of-Flight Mass Spectrometry of Chalcogenide Glasses from (GeSe2)100-x(Sb2Se3)x System
    Sutorova, Katarina
    Prokes, Lubomir
    Nazabal, Virginie
    Bouska, Marek
    Havel, Josef
    Nemec, Petr
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2015, 98 (12) : 4107 - 4110
  • [46] Laser Desorption Ionisation Time-of-Flight Mass Spectrometry of Chalcogenide Glasses from (GeSe2)100-x(Sb2Se3)x System
    Němec, Petr (petr.nemec@upce.cz), 1600, Blackwell Publishing Inc., Postfach 10 11 61, 69451 Weinheim, Boschstrabe 12, 69469 Weinheim, Deutschland, 69469, Germany (98):
  • [47] Glass formation in the GeSe2-Sb2Se3-AgI system
    Vassilev, V.
    Vassilev, G.
    Dikova, J.
    Petkov, K.
    JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 2009, 11 (12): : 2024 - 2028
  • [48] Effect of composition on optical properties of GeSe3-Sb2Se3-ZnSe thin films
    Balboul, M. R.
    Hosni, H. M.
    Soliman, M. A.
    Fayek, S. A.
    BULLETIN OF MATERIALS SCIENCE, 2014, 37 (06) : 1255 - 1263
  • [49] Effect of composition on optical properties of GeSe3-Sb2Se3-ZnSe thin films
    M. R. Balboul
    H. M. Hosni
    M. A. Soliman
    S. A. Fayek
    Bulletin of Materials Science, 2014, 37 : 1255 - 1263
  • [50] Synthesis and properties of new CdSe-AgI-As2Se3 chalcogenide glasses
    Kassem, M.
    Le Coq, D.
    Fourmentin, M.
    Hindle, F.
    Bokova, M.
    Cuisset, A.
    Masselin, P.
    Bychkov, E.
    MATERIALS RESEARCH BULLETIN, 2011, 46 (02) : 210 - 215