Adaptability of the SiNN Pincer Ligand in Iridium and Rhodium Complexes Relevant to Borylation Catalysis

被引：29

作者：

Lee, Chun-I ^{[1
]}

Hirscher, Nathanael A. ^{[1
]}

Zhou, Jia ^{[1
]}

Bhuvanesh, Nattamai ^{[1
]}

Ozerov, Oleg V. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 13期

基金：

美国国家科学基金会;

关键词：

H BOND ACTIVATION; AROMATIC BORYLATION; B BONDS; FUNCTIONALIZATION; ALKANES; ARENES; CLEAVAGE; BORANE; SILANE;

D O I：

10.1021/acs.organomet.5b00125

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A comparison of Rh and Jr complexes of the SiNN ligand (combining Si-H, amido, and quinoline donors) reveals its great degree of adaptability. The amido donor can function as a boryl group acceptor, and the Si-H/metal interaction is highly variable. In contrast to Jr analogues, complexes of Rh do not catalyze dehydrogenative borylation of terminal alkynes but do act as modest benzene borylation catalysts.

引用

页码：3099 / 3102

页数：4

共 50 条

[21] Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand
Segawa, Yasutomo
Yamashita, Makoto
Nozaki, Kyoko
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (26) : 9201 - +
[22] Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand
Hood, Thomas M.
Chaplin, Adrian B.
DALTON TRANSACTIONS, 2021, 50 (07) : 2472 - 2482
[23] Rhodium and Iridium Complexes with a New Scorpionate Phosphane Ligand
Serrano, Angel L.
Casado, Miguel A.
Lopez, Jose A.
Tejel, Cristina
INORGANIC CHEMISTRY, 2013, 52 (13) : 7593 - 7607
[24] Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported by a phenyl-substituted PNP pincer ligand
Calimano, Elisa
Tilley, T. Don
DALTON TRANSACTIONS, 2010, 39 (39) : 9250 - 9263
[25] POP-Pincer Silyl Complexes of Group 9: Rhodium versus Iridium
Esteruelas, Miguel A.
Olivan, Montserrat
Velez, Andrea
INORGANIC CHEMISTRY, 2013, 52 (20) : 12108 - 12119
[26] Cobalt Pincer Complexes in Catalytic C-H Borylation: The Pincer Ligand Flips Rather Than Dearomatizes
Li, Haixia
Obligacion, Jennifer V.
Chirik, Paul J.
Hall, Michael B.
ACS CATALYSIS, 2018, 8 (11): : 10606 - 10618
[27] Determination of metal-ligand bond energies for pincer iridium complexes
Field, Kathleen D.
Bano, Samreen
Kundu, Sabuj
Krogh-Jespersen, Karsten
Goldman, Alan S.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[28] Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand
Poole, Ethan W.
Bustos, Itxaso
Hood, Thomas M.
Smart, Jennifer E.
Chaplin, Adrian B.
DALTON TRANSACTIONS, 2023, 52 (04) : 1096 - 1104
[29] Synthesis and reactivity studies of rhodium complexes supported by a PNSi pincer ligand
Morse, Benjamin
Pell, Christopher
Ozerov, Oleg
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[30] RHODIUM AND IRIDIUM COMPLEXES OF A BINUCLEATING SCHIFF-BASE LIGAND
KUMAR, R
FRONCZEK, FR
MAVERICK, AW
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 : 297 - INOR

← 1 2 3 4 5 →