Salts dissolved in salts: ionic liquid mixtures

被引:163
|
作者
Lui, Matthew Y. [1 ]
Crowhurst, Lorna [1 ]
Hallett, Jason P. [1 ]
Hunt, Patricia A. [1 ]
Niedermeyer, Heiko [1 ]
Welton, Tom [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
基金
英国工程与自然科学研究理事会; 欧洲研究理事会;
关键词
BASIS-SET; TEMPERATURE; SOLVENT; POLARITY; NUCLEOPHILES;
D O I
10.1039/c1sc00227a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solvents and solutions are ubiquitous in chemistry. For instance, in synthesis the solvent allows reagents to mix intimately so that reactions between these may occur. Consequently, understanding how solutes behave in solutions has been one of the major themes of chemistry throughout its history. Ionic liquids (liquid salts) are an exciting recent addition to the range of available solvents. Here we show that these solvents interact with dissolved salts to give solutions that are completely different from those of salts in either traditional organic solvents or water. Observations of these ideal salt solutions will require new models of solvation and polarity and have the potential to lead to new chemical processes.
引用
收藏
页码:1491 / 1496
页数:6
相关论文
共 50 条
  • [31] Flavylium Salts: A Blooming Core for Bioinspired Ionic Liquid Crystals
    Forschner, Robert
    Knelles, Jakob
    Bader, Korinna
    Mueller, Carsten
    Frey, Wolfgang
    Koehn, Andreas
    Molard, Yann
    Giesselmann, Frank
    Laschat, Sabine
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (56) : 12966 - 12980
  • [32] Photoresponsive ionic liquid crystals based on azobenzene guanidinium salts
    Wuckert, Eugen
    Harjung, Marc D.
    Kapernaum, Nadia
    Mueller, Carsten
    Frey, Wolfgang
    Baro, Angelika
    Giesselmann, Frank
    Laschat, Sabine
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (13) : 8382 - 8392
  • [33] Ionic liquid analogues formed from hydrated metal salts
    Abbott, AP
    Capper, G
    Davies, DL
    Rasheed, RK
    CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (15) : 3769 - 3774
  • [34] Room-Temperature Electrodeposition of Mg Metal from Amide Salts Dissolved in Glyme-Ionic Liquid Mixture
    Kitada, Atsushi
    Kang, Yuu
    Uchimoto, Yoshiharu
    Murase, Kuniaki
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2014, 161 (03) : D102 - D106
  • [35] Corrosion Resistance of Steel in Ethanol Containing Ionic Liquid Salts
    Zhao, Z.
    Shao, Y.
    Wang, T.
    Feng, D.
    Liu, W.
    CORROSION, 2009, 65 (10) : 674 - 680
  • [36] Luminescent Ionic Liquid Crystals Based on Tripodal Pyridinium Salts
    Tanabe, Kana
    Yasuda, Takuma
    Kato, Takashi
    CHEMISTRY LETTERS, 2008, 37 (12) : 1208 - 1209
  • [37] Azobenzene-Based Organic Salts with Ionic Liquid and Liquid Crystalline Properties
    Stappert, Kathrin
    Muthmann, Johanna
    Spielberg, Eike T.
    Mudring, Anja-Verena
    CRYSTAL GROWTH & DESIGN, 2015, 15 (09) : 4701 - 4712
  • [38] The visible refraction and dispersion of dissolved salts in water, particularly coloured salts
    Limann, G
    ZEITSCHRIFT FUR PHYSIK, 1921, 8 : 13 - 19
  • [39] DETERMINATION OF AMMONIUM SALTS IN ACID MIXTURES CONTAINING GUANIDINE SALTS
    WILLIAMS, RW
    STALCUP, H
    FAUTH, MI
    ANALYTICAL CHEMISTRY, 1957, 29 (09) : 1356 - 1357
  • [40] MIXED IONIC EXTRACTANTS - ORGANIC SALTS AS EXTRACTANTS FOR INORGANIC SALTS
    GRINSTEA.RR
    DAVIS, JC
    CHARLESW.RK
    LYNN, S
    JOURNAL OF METALS, 1968, 20 (12): : A51 - &