Salts dissolved in salts: ionic liquid mixtures

被引:163
|
作者
Lui, Matthew Y. [1 ]
Crowhurst, Lorna [1 ]
Hallett, Jason P. [1 ]
Hunt, Patricia A. [1 ]
Niedermeyer, Heiko [1 ]
Welton, Tom [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
基金
英国工程与自然科学研究理事会; 欧洲研究理事会;
关键词
BASIS-SET; TEMPERATURE; SOLVENT; POLARITY; NUCLEOPHILES;
D O I
10.1039/c1sc00227a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solvents and solutions are ubiquitous in chemistry. For instance, in synthesis the solvent allows reagents to mix intimately so that reactions between these may occur. Consequently, understanding how solutes behave in solutions has been one of the major themes of chemistry throughout its history. Ionic liquids (liquid salts) are an exciting recent addition to the range of available solvents. Here we show that these solvents interact with dissolved salts to give solutions that are completely different from those of salts in either traditional organic solvents or water. Observations of these ideal salt solutions will require new models of solvation and polarity and have the potential to lead to new chemical processes.
引用
收藏
页码:1491 / 1496
页数:6
相关论文
共 50 条
  • [1] Lithium Salts Dissolved in EMIM Ionic Liquid
    Vondrak, J.
    Sedlarikova, M.
    Maca, J.
    Smilek, J.
    19TH INTERNATIONAL CONFERENCE ON ADVANCED BATTERIES, ACCUMULATORS AND FUEL CELLS (ABAF 2018), 2018, 87 (01): : 59 - 65
  • [2] The solubility and conductivity of lithium salts in ionic liquid mixtures
    Hamilton, John L.
    Gross, Stephen M.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 158 - 158
  • [3] Ionic liquid crystals: hexafluorophosphate salts
    Gordon, CM
    Holbrey, JD
    Kennedy, AR
    Seddon, KR
    JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (12) : 2627 - 2636
  • [4] Mixing ionic liquids - "simple mixtures" or "double salts"?
    Chatel, Gregory
    Pereira, Jorge F. B.
    Debbeti, Varun
    Wang, Hui
    Rogers, Robin D.
    GREEN CHEMISTRY, 2014, 16 (04) : 2051 - 2083
  • [6] INFLUENCE OF DISSOLVED SALTS ON INFRARED SPECTRA OF LIQUID AMMONIA
    CORSET, J
    HUONG, PV
    LASCOMBE, J
    SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1968, A 24 (09): : 1385 - &
  • [7] Ionic liquid S-alkylthiouronium salts
    Abai, Mahpuzah
    Holbrey, John D.
    Rogers, Robin D.
    Srinivasan, Geetha
    NEW JOURNAL OF CHEMISTRY, 2010, 34 (09) : 1981 - 1993
  • [8] DIELECTRIC RELAXATION IN LIQUID AMMONIA AND EFFECT OF DISSOLVED SALTS ON IT
    APFEL, H
    BREITSCH.K
    SCHMIDT, W
    BERICHTE DER BUNSEN-GESELLSCHAFT FUR PHYSIKALISCHE CHEMIE, 1968, 72 (08): : 1059 - &
  • [9] The electrolysis of dissolved salts
    Lorenz, R
    ZEITSCHRIFT FUR ANORGANISCHE CHEMIE, 1900, 23 (02): : 97 - 110
  • [10] On the physical properties of mixtures of nitrate salts and protic ionic liquids
    Vallet, Pablo
    Bouzon-Capelo, Silvia
    Mendez-Morales, Trinidad
    Gomez-Gonzalez, Victor
    Arosa, Yago
    de la Fuente, Raul
    Lopez-Lago, Elena
    Rodriguez, Julio R.
    Gallego, Luis J.
    Parajo, Juan J.
    Salgado, Josefa
    Turmine, Mireille
    Segade, Luisa
    Cabeza, Oscar
    Varela, Luis M.
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 350