Multi-addressable fluorescence switch based on a new photochromic diarylethene with two rhodamine B units

被引:6
|
作者
Tang, Yongjuan [1 ]
Cui, Shiqiang [1 ]
Pu, Shouzhi [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
基金
中国国家自然科学基金;
关键词
Diarylethene; Rhodamine B; Photochromism; Multi-addressable; Fluorescence switch; Logic circuit; PHOTOINDUCED ELECTRON-TRANSFER; DUAL-CONTROL; CHEMOSENSOR; BEARING; PROTON; PHOTO; LIGHT;
D O I
10.1016/j.tet.2016.06.006
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel diarylethene derivative with two rhodamine B units has been synthesized successfully. The diarylethene could be effectively controlled by the stimulation of light, proton, and metal ions. The fluorescence intensity of the diarylethene was enhanced upon addition of TFA, Al3+, Cr3+, and Fe3+, which was assigned to the blocked FRET process by the protonation of the rhodamine or complexation with Al3+, Cr3+, and Fe3+. The results indicated that the diarylethene could act as a multi-addressable fluorescence switch with the light, proton, and metal ions stimulus. Moreover, two logic circuits were constructed with the fluorescence intensity as the output signal responding to the light and chemical species as the inputs. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4400 / 4407
页数:8
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