Oxidative Cleavage of Functionalized Cyclic Olefins with H2O2 Using a Peroxotungstate Complex

被引：4
|
作者：
Ford, Mark J. [1 ]
Kohlhepp, Helmut [1 ]
Miller, Stephen [1 ]
Riess, Sven [1 ]
Schmidt, Jan Peter [1 ]
Wisplinghoff, Lothar [1 ]
机构：
[1] Bayer CropSci AG, D-65926 Frankfurt, Germany
来源：
ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2011年 / 15卷 / 04期
关键词：
HYDROGEN-PEROXIDE; ADIPIC ACID; CARBOXYLIC-ACIDS;
D O I：
10.1021/op200130d
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The oxidative cleavage of functionalized cyclic olefins with aqueous hydrogen peroxide was studied. A mild protocol was developed using a readily available diperoxotungstate catalyst that allowed otherwise unstable functionalities to be present during the oxidation. During the optimization of the procedure (3R*,4R*)-3-[(benzyloxy)carbonyl]-4-(ethoxycarbonyl)hexanedioic add was synthesized on a 400 g scale furnishing the product in 7996 yield.
引用
收藏
页码：883 / 885
页数：3
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