Bu4NI-Catalyzed Dehydrogenative Coupling of Diary! Phosphinic Acids with C(sp3)-H Bonds of Arenes

被引：23
|
作者：
Xiong, Biquan [1 ]
Wang, Gang [1 ]
Zhou, Congshan [1 ]
Liu, Yu [1 ]
Zhang, Panliang [1 ]
Tang, Kewen [1 ]
机构：
[1] Hunan Inst Sci & Technol, Dept Chem & Chem Engn, Yueyang 414006, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 02期
基金：
中国国家自然科学基金;
关键词：
COPPER-CATALYZED SYNTHESIS; P(O)-OH COMPOUNDS; DIRECT ESTERIFICATION; PHOSPHORIC-ACID; ALCOHOLS; ESTERS; PHOSPHORYLATION; ARYLATION; EFFICIENT; PHOSPHAISOCOUMARINS;
D O I：
10.1021/acs.joc.7b02422
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient phosphorylation of C(sp(3)) H bonds of arenes with diaryl phosphinic acids via Bu4NI-catalyzed dehydrogenative coupling has been developed. This transformation proceeds efficiently under transition-metal-free reaction conditions and represents a straightforward method to prepare valuable organophosphorus compounds from readily available arenes and diaryl phosphinic acids.
引用
收藏
页码：993 / 999
页数：7
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