Compound representatives of a new type of triterpenoid from Aglaia odorata

被引：18
|
作者：
Cai, XH [1 ]
Luo, XD
Zhou, J
Hao, XJ
机构：
[1] Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 14期
关键词：
D O I：
10.1021/ol050805h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel triterpenoid, 21,25-cyclodammar-20(22)-ene-3 beta,24 alpha-diol, has been isolated from Aglaia odorata. Its structure was elucidated on the basis of 1D- and 2D-NMR and MS spectra and then confirmed by X-ray diffraction. It represents a new type of natural five-membered-ring triterpenoid, named cyclodammarane. Its possible biopathway was that squalene-2,3;22,23-diepioxide was directly cyclized to form 24,25-epoxydammar-20(21)-en-3-ol, followed by protonation of the remaining 24,25-epoxide and the cation attacking 21(20) methylene to generate the E ring.
引用
收藏
页码：2877 / 2879
页数：3
相关论文
共 50 条
  • [21] Dammarane-Type Triterpenoid from the Stem Bark of Aglaia elliptica (Meliaceae) and Its Cytotoxic Activities
    Farabi, Kindi
    Harneti, Desi
    Darwati
    Mayanti, Tri
    Nurlelasari
    Maharani, Rani
    Sari, Aprilia Permata
    Herlina, Tati
    Hidayat, Ace Tatang
    Supratman, Unang
    Fajriah, Sofa
    Azmi, Mohamad Nurul
    Shiono, Yoshihito
    MOLECULES, 2022, 27 (19):
  • [22] Anti-inflammatoty constituents from the stems of Aglaia odorata Lour.
    Kim, Y. M.
    Seo, J. S.
    Oh, S. R.
    Lee, H. K.
    Chin, Y. W.
    PLANTA MEDICA, 2012, 78 (11) : 1242 - 1242
  • [23] Natural anti-neuroinflammatory inhibitors in vitro and in vivo from Aglaia odorata
    Yin, Qianqian
    Chen, Gang
    Mu, Danyang
    Yang, Yuxin
    Hao, Jinle
    Lin, Bin
    Zhou, Di
    Hou, Yue
    Li, Ning
    BIOORGANIC CHEMISTRY, 2024, 147
  • [24] Lysobacter terrae sp nov isolated from Aglaia odorata rhizosphere soil
    Ngo, Hien T. T.
    Won, KyungHwa
    Du, Juan
    Son, Heung-Min
    Park, YongJin
    Kook, MooChang
    Kim, Ki-Young
    Jin, Feng-Xie
    Yi, Tae-Hoo
    INTERNATIONAL JOURNAL OF SYSTEMATIC AND EVOLUTIONARY MICROBIOLOGY, 2015, 65 : 587 - 592
  • [25] Constituents of the flower essential oil of Aglaia odorata Lour. from Vietnam
    Weyerstahl, P
    Marschall, H
    Son, PT
    Giang, PM
    FLAVOUR AND FRAGRANCE JOURNAL, 1999, 14 (04) : 219 - 224
  • [26] A new nemoralisin-type diterpenoid from Aglaia lawii
    Pham, Quan H.
    Nguyen, Van T. K.
    Pham-Tran, Nguyen-Nguyen
    Trinh, Binh T. D.
    Nguyen, Ly T. T.
    Nguyen, Le-Thu T.
    Pham, Ngoc T. T.
    Nguyen, Lien-Hoa D.
    Ngo, Ngoc T. N.
    NATURAL PRODUCT RESEARCH, 2025,
  • [27] A new triterpenoid compound from stems and leaves of American ginseng
    Han, Liu
    Li, Zhuo
    Zheng, Qian
    Liu, Jin-Ping
    Li, Ping-Ya
    NATURAL PRODUCT RESEARCH, 2016, 30 (01) : 13 - 19
  • [28] Diterpenoids and triterpenoids with potential anti-inflammatory activity from the leaves of Aglaia odorata
    Yodsaoue, Orapun
    Sonprasit, Jarinthon
    Karalai, Chatchanok
    Ponglimanont, Chanita
    Tewtrakul, Supinya
    Chantrapromma, Suchada
    PHYTOCHEMISTRY, 2012, 76 : 83 - 91
  • [29] INSECTICIDAL 1H-CYCLOPENTATETRAHYDRO[B]BENZOFURANS FROM AGLAIA-ODORATA
    ISHIBASHI, F
    SATASOOK, C
    ISMAN, MB
    TOWERS, GHN
    PHYTOCHEMISTRY, 1993, 32 (02) : 307 - 310
  • [30] Aglacins A-D, first representatives of a new class of aryltetralin cyclic ether lignans from Aglaia cordata
    Wang, BG
    Ebel, R
    Nugroho, BW
    Prijono, D
    Frank, W
    Steube, KG
    Hao, XJ
    Proksch, P
    JOURNAL OF NATURAL PRODUCTS, 2001, 64 (12): : 1521 - 1526
12345