Amino-Functionalized Water-Stable Metal-Organic Framework for Enhanced C2H2/CH4 Separation Performance

被引：35
|
作者：
Li, Qian [1 ]
Wu, Nana [1 ]
Li, Jia [1 ]
Wu, Dapeng [1 ]
Li, Yanshuo [1 ]
机构：
[1] Ningbo Univ, Sch Mat Sci & Chem Engn, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China
来源：
INORGANIC CHEMISTRY | 2020年 / 59卷 / 05期
基金：
中国国家自然科学基金;
关键词：
SITES; GAS; BINDING;
D O I：
10.1021/acs.inorgchem.9b03295
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Using a hydrothermal method, a water-stable metal-organic framework based on 8-connected Ni-2 units with (4.6(2) )2(4(7).6(13).8(3)) topology, [Ni-2(mu(2)-OH2)(ctpd)(2) (NH2-bdc)]center dot(EtOH)(2)center dot(H2O)(2) (NbU-9-NH2), constructed by mixing a rigid tridentate ligand and an amino-p-carboxyl ligand, displays an enhanced ability for adsorbing C2H2 and adsorptive selectivity for C2H2/CH4. Dispersion-corrected density functional theory calculation confirmed that the enhenced acetylene adsorption is mainly derived from the weak hydrogen-bonding between a hydrogen atom of C2H2 and the nitrogen atom of the amino group.
引用
收藏
页码：2631 / 2635
页数：5
相关论文
共 50 条
  • [31] A flexible-robust metal-organic framework for efficient C2H2/C2H4 separation
    Zhang, Peng
    Yu, Biao
    Jiang, Ke
    Zhang, Ling
    MATERIALS LETTERS, 2023, 353
  • [32] Microporous Cu metal-organic framework constructed from V-shaped tetracarboxylic ligand for selective separation of C2H2/CH4 and C2H2/N2 at room temperature
    Meng, Lingkun
    Liu, Kang
    Fu, Shuang
    Wang, Lei
    Liang, Chen
    Li, Guanghua
    Li, Chunguang
    Shi, Zhan
    JOURNAL OF SOLID STATE CHEMISTRY, 2018, 265 : 285 - 290
  • [33] One Scalable and Stable Metal-Organic Framework for Efficient Separation of CH4/N2 Mixture
    Guo, Pengtao
    Ying, Yunpan
    Liu, Dahuan
    ACS APPLIED MATERIALS & INTERFACES, 2024, 16 (06) : 7338 - 7344
  • [34] An aminopyrimidine-functionalized cage-based metal-organic framework exhibiting highly selective adsorption of C2H2 and CO2 over CH4
    Jiao, Jingjing
    Dou, Li
    Liu, Huimin
    Chen, Fengli
    Bai, Dongjie
    Feng, Yunlong
    Xiong, Shunshun
    Chen, De-Li
    He, Yabing
    DALTON TRANSACTIONS, 2016, 45 (34) : 13373 - 13382
  • [35] A Robust Heterometallic Cd(Ⅱ)/Ba(Ⅱ)-Organic Framework with Exposed Amino Group and Active Sites Exhibiting Excellent CO2/CH4 and C2H2/CH4 Separation
    傅红如
    蒋玉莹
    罗家华
    李婷
    ChineseJournalofStructuralChemistry, 2022, 41 (03) : 287 - 292
  • [36] A microporous metal-organic framework for selective C2H2 and CO2 separation
    Lin, Rong-Guang
    Lin, Rui-Biao
    Chen, Banglin
    JOURNAL OF SOLID STATE CHEMISTRY, 2017, 252 : 138 - 141
  • [37] Ultrathin water-stable metal-organic framework membranes for ion separation
    Jian, Meipeng
    Qiu, Ruosang
    Xia, Yun
    Lu, Jun
    Chen, Yu
    Gu, Qinfen
    Liu, Ruiping
    Hu, Chengzhi
    Qu, Jiuhui
    Wang, Huanting
    Zhang, Xiwang
    SCIENCE ADVANCES, 2020, 6 (23)
  • [38] Three-dimensional copper (II) metal-organic framework with open metal sites and anthracene nucleus for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature
    Duan, Xing
    Cai, Jianfeng
    Yu, Jiancan
    Wu, Chuande
    Cui, Yuanjing
    Yang, Yu
    Qian, Guodong
    MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 181 : 99 - 104
  • [39] Achieving Record C2H2 Packing Density for Highly Efficient C2H2/C2H4 Separation with a Metal-Organic Framework Prepared by a Scalable Synthesis in Water
    Zhang, Xin
    Chen, Qiancheng
    Bai, Xuefeng
    Zhao, Yan-Long
    Li, Jian-Rong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (45)
  • [40] Cu-Based Metal-Organic Frameworks Characterized by V-Shaped Ligands and Application to Efficient Separation of C2H2/CO2 and C2H2/CH4
    Zhang, Miaomiao
    Zhao, Jiashuo
    Li, Siqi
    Luo, Xiaolong
    Zhang, Shi-Tong
    Shao, Yizhi
    Zhu, Xiaofei
    CRYSTAL GROWTH & DESIGN, 2025, 25 (07) : 2002 - 2012
12345