Anthracene coupled thiourea as a colorimetric sensor for F-/Cu2+ and fluorescent sensor for Hg2+/picric acid

被引:39
|
作者
Udhayakumari, Duraisamy [1 ,2 ]
Velmathi, Sivan [1 ,2 ]
Venkatesan, Parthiban [2 ]
Wu, Shu-Pao [2 ]
机构
[1] Natl Inst Technol, Dept Chem, Organ & Polymer Synth Lab, Tiruchirappalli 620015, Tamil Nadu, India
[2] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 300, Taiwan
关键词
Anthracene; Thiourea; Aqueous medium; Picric acid; RAW; 264.7; cells; HG2+ IONS; CHEMOSENSOR; MERCURY; CU2+; RECOGNITION; METHYLATION; CU(II); PROBE;
D O I
10.1016/j.jlumin.2015.01.052
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A new dual chemosensor (Z)-2-(anthracen-9-ylmethylene)-N-phenylhydrazinecarbothioamide R1 was synthesized by incorporating a thiourea derivative as a binding unit and an anthracene group as a fluorescence signalling unit. R1 selectively binds with Cu2+ and He2+ ions in aqueous medium. R1 exhibits highly selective recognition towards F- ion and picric acid in organic medium. Fluorescence quenching was observed in case of R1 with Cu2+ and He+ ions over commonly coexistent metal ions. Furthermore, fluorescence imaging experiments of Cu2+ and Hg2+ ions in living RAW 264.7 cells demonstrate its value of practical applications in biological systems. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:411 / 416
页数:6
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