Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ2 N:N′]dimolybdenum(II) tetrahydrofuran solvate

被引：1
|
作者：
Han, L. -J. [1 ]
机构：
[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
SUPRAMOLECULAR SYNTHONS;
D O I：
10.1107/S1600536811011202
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Mo-2(C13H9N2Br2)(4)]center dot C4H8O, contains a quadruply bonded Mo-2 4+ unit equatorially coordinated by four N,N'-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo-Mo bond is located on a special position with 2/m symmetry. In the crystal, complex molecules are linked by Br...Br interactions [3.7049 (10) A]. The disordered solvent molecule could not be satisfactorily modelled and was therefore eliminated from the final refinement.
引用
收藏
页码：M514 / U1134
页数：11
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