Recent advances in oxidation catalysis using ionic liquids as solvents

被引:106
|
作者
Betz, Daniel [1 ]
Altmann, Philipp
Cokoja, Mirza [1 ]
Herrmann, Wolfgang A. [1 ]
Kuehn, Fritz E. [1 ]
机构
[1] Tech Univ Munich, Chair Inorgan Chem, Catalysis Res Ctr, D-85747 Garching, Germany
关键词
Ionic liquids; Two-phase catalysis; Transition metal catalysts; Oxidation; SELECTIVE AEROBIC OXIDATION; BAEYER-VILLIGER OXIDATION; SCHIFF-BASE COMPLEXES; DEEP DESULFURIZATION; MILD OXIDATION; HOMOGENEOUS CATALYSIS; HYDROGEN-PEROXIDE; MOLECULAR-OXYGEN; HIGHLY EFFICIENT; GREEN OXIDATION;
D O I
10.1016/j.ccr.2010.12.004
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Ionic liquids are an interesting alternative to classical solvents presenting several advantages. A variety of catalysts show good or even enhanced activities when applied in ionic liquids. Oxidation catalysis represents a large segment of industrial chemistry, providing both bulk chemicals and intermediates for high value added special products and pharmaceuticals. Particularly for the latter products organometallic and inorganic catalysts are being developed that can be applied in systems consisting of or containing ionic liquids. This work provides an overview on recent developments in this field. (C) 2011 Published by Elsevier B.V.
引用
收藏
页码:1518 / 1540
页数:23
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