New zeotype borophosphates with chiral tetrahedral topology:: (H)0.5M1.25(H2O)1.5[BP2O8]•H2O (M = Co(II) and Mn(II))

被引：10

作者：

Yilmaz, A ^{[1
]}

Yildirim, LT

Bu, X

Kizilyalli, M

Stucky, GD

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

[2] Hacettepe Univ, Dept Engn Phys, TR-06800 Ankara, Turkey

[3] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

[4] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 2005年 / 40卷 / 06期

关键词：

borophosphate; molecular sieve; microporous; zeotype; phosphate; boron; manganese; cobalt; crystal structure;

D O I：

10.1002/crat.200410386

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Two new isostructural open-framework zeotype transition metal borophosphate compounds, (H)(0.5)M-1.25(H2O)(1.5)[BP2O8].H2O (M=Co(II) and Mn(II)) were synthesized by mild hydrothermal method. The structure of compounds were characterized by single-crystal X-ray diffraction which have ordered, alternating, vertex-sharing BO4, PO4, and (MO4)OM(H2O)(2) groups with hexagonal, P 6(1) 2 2 (No 178) space group and unit cell parameters for Co a= 9.4960(6) angstrom, c= 15.6230(13) angstrom, for Mn a= 9.6547(12) angstrom, c= 15.791(3) angstrom, Z=1 for both of them. TGA/DTA analysis, IR spectroscopy were used for characterization. Magnetic susceptibility measurements for both of the compound indicate strong antiferromagnetic interaction between metal centers.

引用

页码：579 / 585

页数：7

共 50 条

[41] Investigation of the chiral properties of configurations of (H2O)n, K+(H2O)m, and Na+(H2O)m (n = 4–8, m = 5–10) small water clusters at 1 K
A. V. Khakhalin
O. N. Gradoboeva
Moscow University Physics Bulletin, 2016, 71 : 413 - 419
[42] Synthesis and structure of the first protonated zincoborophosphate:: (H3O)Zn(H2O)2BP2O8•H2O
Shi, HZ
Shan, YK
He, MY
Liu, YY
Weng, LH
CHINESE JOURNAL OF CHEMISTRY, 2003, 21 (09) : 1170 - 1173
[43] Synthesis and Structure of the First Protonated Zincoborophosphate: （H3O）Zn（H2O）2BP2O8·H2O
石恒真
单永奎
何鸣元
刘煜炎
翁林红
ChineseJournalofChemistry, 2003, (09) : 1170 - 1173
[44] Magnetic Dimensionality of Metal Formate M[(H2O)2(HCOO)2] Compounds (M = Co(II), Cu(II))
Sousa, L. L. L.
Barbosa, G. F.
Machado, F. L. A.
Araujo, L. R. S.
Brandao, P.
Reis, M. S.
Rocco, D. L.
IEEE TRANSACTIONS ON MAGNETICS, 2013, 49 (12) : 5610 - 5615
[45] Rare-earth-metal coordination polymers:: Synthesis and crystal structures of five new adipinates, [M2(Adi)3(H2O)4](AdiH2)(H2O)4 (M = La, Nd), [Er(Adi)(H2O)5]Cl(H2O) and [M(Adi)(H2O)5](NO3)(H2O) (M = Gd, Er)
Bromant, C
Flemig, H
Nika, W
Pantenburg, I
Meyer, G
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (05): : 851 - 858
[46] Preparation and characterization of the layered borophosphates MII(H2O)2[B2P2O8(OH)2]•H2O (MII = Fe, Co, Ni)
Menezes, Prashanth W.
Hoffmann, Stefan
Prots, Yurii
Schnelle, Walter
Kniep, Ruediger
INORGANICA CHIMICA ACTA, 2010, 363 (15) : 4299 - 4306
[47] REARRANGEMENTS OF MODEL (H2O)8 AND (H2O)20 CLUSTERS
WALES, DJ
OHMINE, I
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (09): : 7257 - 7268
[48] Structural patterns and dimensionality in magnesium borophosphates:: The crystal structures of Mg2(H2O)[BP3O9(OH)4] and Mg(H2O)2[B2P2O8(OH)2]•H2O
Ewald, B
Öztan, Y
Prots, Y
Kniep, R
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (09): : 1615 - 1621
[49] THE EQUILIBRIUM COEFFICIENT OF COCRYSTALLIZATION IN THE ZNC2O4.2H2O-MN(II)-H2O SYSTEM
BERDONOSOVA, BG
PENCHEVA, Z
BURLAKOVA, EV
SOVIET RADIOCHEMISTRY, 1984, 26 (01): : 10 - 13
[50] Melting behavior of the (H2O)6 and (H2O)8 clusters
Pedulla, JM
Jordan, KD
CHEMICAL PHYSICS, 1998, 239 (1-3) : 593 - 601

← 1 2 3 4 5 →