Photoresponsive tweezers for alkali metal ions. Photochromic diarylethenes having two crown ether moieties

被引：98

作者：

Takeshita, M ^{[1
]}

Irie, M ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Biochem & Chem, Higashi Ku, Fukuoka 8128581, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 63卷 / 19期

关键词：

D O I：

10.1021/jo980290q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkali metal ion extraction was carried out using photochromic dithienylethene having two benzo-12-crown-4 ethers (1), benzo-15-crown-5 ethers (2), or benzo-18-crown-6 ethers moieties (3) and bis(benzothienyl)ethene having two benzo-18-crown-6 ether moieties (4). Two crown ether moieties of the open-ring form captured large metal ions cooperatively like tweezers, while the photogenerated closed-ring form released the ions. The reduced affinities for metal picrates were fully recovered by irradiation with visible light (>480 nm). The H-1 NMR spectrum measurement of the solutions (CDCl3/CD3CN: 5/1) containing both alkali metal picrates and 2 or 3 confirmed that the large alkali metal ions were captured by the two intramolecular crown ethers,

引用

页码：6643 / 6649

页数：7

共 50 条

[21] Conduction of alkali metal cations in poly(diaza-crown ether)s having hydroxyethyl side arms
Ohno, Hiroyuki, 1600, Butterworth-Heinemann Ltd, Oxford, United Kingdom (35):
[22] Synthesis and intramolecular charge transfer of bipyridinium-crown ether conjugates in response to alkali metal ions
Kuwabara, Tetsuo
Guo, Haocheng
Okubo, Tadahiko
Orii, Hiroki
Sugiyama, Kosuke
Miyajima, Naoya
Suzuki, Yasutada
TETRAHEDRON, 2013, 69 (20) : 4081 - 4087
[23] A novel approach towards crown-ether modified polyimides with affinity for alkali metal ions recognition
Chiriac, Adriana-Petronela
Damaceanu, Mariana-Dana
JOURNAL OF MOLECULAR LIQUIDS, 2021, 322
[24] NEW PHOTOMETRIC REAGENTS FOR ALKALI-METAL IONS BASED ON CROWN ETHER COMPLEX-FORMATION
NAKAMURA, H
SAKA, H
TAKAGI, M
UENO, K
CHEMISTRY LETTERS, 1981, (09) : 1305 - 1306
[25] Thermodynamic studies of crown-ether complexes with alkali-metal and ammonium ions in various solvents
Ohtsu, K
BUNSEKI KAGAKU, 1997, 46 (02) : 167 - 168
[26] KINETICS OF COMPLEXATION OF ALKALI EARTH METAL-IONS WITH 18-CROWN-6-ETHER IN METHANOL
YUN, SS
KIM, SH
YANG, JM
CHOI, KY
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1989, 10 (02) : 155 - 158
[27] Crown ether-facilitated transfers of alkali metal ions across the water-nitrobenzene interface
PANG Zhi-Chen
GUO Du
TEN Xiu-Juan
WANG Er-Kang Changchun Institute of Applied Chemistry
Acta Chimica Sinica(English Edition), 1985, (03) : 194 - 200
[28] Synthesis and Characterization of Alkali Metal Ion-Binding Copolymers Bearing Dibenzo-24-crown-8 Ether Moieties
Wang, Da-Ming
Aso, Yuji
Ohara, Hitomi
Tanaka, Tomonari
POLYMERS, 2018, 10 (10):
[29] PREPARATION OF A NOVEL POLYMERIC COPPER PHTHALOCYANINE CONTAINING CROWN-ETHER MOIETIES AND ITS ALKALI-METAL BINDING PROPERTY
AHSEN, V
YILMAZER, E
BEKAROGLU, O
GUL, A
BEKAROGLU, O
MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1987, 8 (05): : 243 - 246
[30] CONDUCTION OF ALKALI-METAL CATIONS IN POLY(DIAZA-CROWN ETHER)S HAVING HYDROXYETHYL SIDE ARMS
OHNO, H
INOUE, Y
TSUKUBE, H
POLYMER, 1994, 35 (26) : 5753 - 5757

← 1 2 3 4 5 →