Design and fabrication of ultrathin and highly thermal-stable α-Ta/graded Ta(N)/TaN multilayer as diffusion barrier for Cu interconnects

被引:5
|
作者
Liu, C. H. [1 ]
Wang, Y. [1 ]
Liu, B. [1 ]
An, Z. [1 ]
Song, Z. X. [2 ]
Xu, K. W. [2 ]
机构
[1] Sichuan Univ, Inst Nucl Sci & Technol, Minist Educ, Key Lab Radiat Phys & Technol, Chengdu 610064, Peoples R China
[2] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
基金
中国国家自然科学基金;
关键词
TANTALUM FILMS; THIN-FILMS; STABILITY; LAYER; TA; MODEL; BETA;
D O I
10.1088/0022-3727/44/7/075302
中图分类号
O59 [应用物理学];
学科分类号
摘要
A one-step strategy of magnetron sputtering deposition with dynamic regulation of sputtering atmosphere was developed to prepare alpha-Ta/graded Ta(N)/TaN multilayer films on the Si substrate. The evolution of Ta clusters shows a significant effect on the crystal structure of the Ta film. The experimental results validate that the formation of alpha-Ta was attributed to the nucleation of larger Ta clusters. After being annealed at 600 degrees C, the alpha-Ta/graded Ta(N)/TaN multilayer film can still effectively block the diffusion of Cu. The mechanisms of the forming of the alpha-Ta and the thermal stability of the film stacks are characterized in detail.
引用
收藏
页数:6
相关论文
共 49 条
  • [31] Effects of N doping in Ru-Ta alloy barrier on film property and reliability for Cu interconnects
    Torazawa, Naoki
    Hinomura, Toru
    Mori, Kenichi
    Koyama, Yuki
    Hirao, Shuji
    Kobori, Etsuyoshi
    Korogi, Hayato
    Maekawa, Kazuyoshi
    Tomita, Kazuo
    Chibahara, Hiroyuki
    Suzumura, Naohito
    Asai, Koyu
    Miyatake, Hiroshi
    Matsumoto, Susumu
    PROCEEDINGS OF THE 2009 IEEE INTERNATIONAL INTERCONNECT TECHNOLOGY CONFERENCE, 2009, : 113 - 115
  • [32] AUGER-ELECTRON SPECTROSCOPY STUDY ON THE STABILITY AND THE INTERFACIAL REACTION OF TA, TA-N AND TAN FILMS AS A DIFFUSION BARRIER BETWEEN CU9AL4 FILM AND SI
    NOYA, A
    SASAKI, K
    TAKEYAMA, M
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 (02): : 911 - 915
  • [33] Atomic layer deposition of amorphous Ni-Ta-N films for Cu diffusion barrier
    Wang, Yong-Ping
    Ding, Zi-Jun
    Zhu, Bao
    Liu, Wen-Jun
    Zhang, David Wei
    Ding, Shi-Jin
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2018, 36 (03):
  • [34] Diffusion barrier performance of W/Ta-W-N double layers for Cu metallization
    Song, SX
    Liu, YZ
    Li, M
    Mao, DL
    Chang, CK
    Ling, HQ
    MICROELECTRONIC ENGINEERING, 2006, 83 (03) : 423 - 427
  • [35] Effect of a Ta-Si-N diffusion barrier on the texture formation in thin Cu films
    Huebner, R.
    JOURNAL OF APPLIED PHYSICS, 2007, 101 (09)
  • [36] Diffusion barrier performance of reactively sputtered Ta-W-N between Cu and Si
    Liu, YZ
    Song, SX
    Mao, DL
    Ling, HQ
    Li, M
    MICROELECTRONIC ENGINEERING, 2004, 75 (03) : 309 - 315
  • [37] In Situ Ramp Anneal X-ray Diffraction Study of Atomic Layer Deposited Ultrathin TaN and Ta1-xAlxNy Films for Cu Diffusion Barrier Applications
    Consiglio, S.
    Dey, S.
    Yu, K.
    Tapily, K.
    Clark, R. D.
    Hasegawa, T.
    Wajda, C. S.
    Leusink, G. J.
    Diebold, A. C.
    ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2016, 5 (09) : P509 - P513
  • [38] Highly thermal-stable, plasma-polymerized BCB polymer film (k=2.6) for Cu dual-damascene interconnects
    Kawahara, J
    Shiba, K
    Tagami, M
    Tada, M
    Saito, S
    Onodera, T
    Kinoshita, K
    Hiroi, M
    Furuya, A
    Kikuta, K
    Hayashi, Y
    2000 SYMPOSIUM ON VLSI TECHNOLOGY, DIGEST OF TECHNICAL PAPERS, 2000, : 20 - 21
  • [39] Effect of thin Zr layer insertion on the Ta-N diffusion barrier performance in Cu metallization
    Ding, Minghui
    Zhang, Lili
    Gai, Dengyu
    Wang, Ying
    Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering, 2009, 38 (11): : 2036 - 2038
  • [40] Effect of Thin Zr Layer Insertion on the Ta-N Diffusion Barrier Performance in Cu Metallization
    Ding Minghui
    Zhang Lili
    Gai Dengyu
    Wang Ying
    RARE METAL MATERIALS AND ENGINEERING, 2009, 38 (11) : 2036 - 2038