Graphene based ceria nanocomposite synthesized by hydrothermal method for enhanced supercapacitor performance

被引:24
|
作者
Britto, Sheeba [1 ,2 ]
Ramasamy, Velavan [2 ]
Murugesan, Priya [1 ,3 ]
Neppolian, Bernaurdshaw [4 ]
Kavinkumar, Thangavel [4 ]
机构
[1] Bharathiyar Univ, R&D Ctr, Coimbatore, Tamil Nadu, India
[2] Bharath Inst Higher Educ & Res, Dept Phys, Chennai, Tamil Nadu, India
[3] Saveetha Coll Engn, Dept Phys, Chennai, Tamil Nadu, India
[4] SRM Inst Sci & Technol, Res Dept, Chennai, Tamil Nadu, India
关键词
Graphene oxide; Reduced graphene oxide; Cerium oxide; Electrochemical studies; Cyclic voltametry; Galvanostatic charge/discharge; Supercapacitors; ELECTROCHEMICAL PROPERTIES; FACILE SYNTHESIS; OXIDE HYBRIDS; NANOPARTICLES; COMPOSITE; CEO2; FABRICATION; MORPHOLOGY; ENERGY;
D O I
10.1016/j.diamond.2020.107808
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Reduced graphene oxide - cerium oxide (rGO-CeO2) nanocomposite is prepared by simple hydrothermal method for enhanced charge storage supercapacitor performance. The prepared nanocomposite is characterized by various techniques, such as X-ray diffraction (XRD), Fourier Transform - Raman Spectra (FT-Raman), Field Emission - Scanning Electron Microscope (FE-SEM), High Resolution -Transmission Electron Microscope (HR-TEM), Thermo-gravimetric and Differential Thermal Analysis (TG-DTA), Cyclic Voltametric (CV), Galvanostatic Charge/Discharge (GCD) and Electrochemical Impedance Spectroscopy (EIS) studies to understand its morphology, composition, thermal stability and charge storage efficiency as electrode material. The nanocomposite formation is confirmed with FE-SEM and HR-TEM images where the ceria is anchored on the surface of the graphene sheets and the interplanar distances are observed as fringes. The Energy Dispersive Analysis of X-Ray (EDAX) has provided substantial evidence for the nanocomposite formation with the elemental composition. The maximum specific capacitance is measured as 280 F/g using GCD studies. The surface area of the nanocomposite is determined using the Brunauer-Emmett-Teller (BET) analysis.
引用
收藏
页数:9
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