Effect of sintering time on corrosion behavior of an Ag/Al/Nb/Ti/Zn alloy system

被引:10
|
作者
Rodrigues, Joao Felipe Q. [1 ]
Padilha, Giovana S. [1 ]
Bortolozo, Ausdinir D. [1 ,2 ]
Osorio, Wislei R. [1 ,2 ]
机构
[1] Univ Estadual Campinas, Sch Appl Sci FCA, Res Grp Mfg Adv Mat, UNICAMP, Campus 2, Limeira, SP, Brazil
[2] Univ Estadual Campinas, Sch Technol, UNICAMP, Campus 1, BR-13484332 Limeira, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
High-entropy alloy; Impedance; Polarization; Discontinuous reinforcing particles; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; IN-VITRO DEGRADATION; ZN-MG ALLOYS; MECHANICAL-PROPERTIES; GALVANIC CORROSION; MICROSTRUCTURE; NACL; NB; ELECTRODES; THICKNESS;
D O I
10.1016/j.jallcom.2020.155039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-entropy alloys are interesting for both aerospace and biomedical applications. Additionally, their application into a corrosive environment is also demanded. Investigations concerning to the effects in the sintering time on the microstructural features of an AgAlNbTiZn alloy system and correlating with corrosion behavior are scarce. This investigation is focused on the evaluation of the corrosion behavior of an AgAlNbTiZn alloy system in a 0.5 M NaCl solution at 25 degrees C. Experimental and simulated EIS parameters and potentiodynamic polarization curves are discussed. It is found that both the dispersed-Nb particles and the TiAl intermetallics constitute the microstructural arrays affecting significantly the cathode-to-anode area ratio. Consequently, the corrosion behavior is also substantially modified. It is also found that the sintered sample during 12 h reveals some colonies of the TiAl intermetallic interfacing with the Nb powder particles. These are lower (similar to 3x) than the sintered sample for 24 h. This evidences that the microstructural array has an important role on the corrosion current density and polarization resistance of the samples examined. (c) 2020 Elsevier B.V. All rights reserved.
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页数:15
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