X-ray Fluorescence Spectroscopy Features of Micro- and Nanoscale Copper and Nickel Particle Compositions

被引：8

作者：

Chebakova, Kristina A. ^{[1
]}

Dzidziguri, Ella L. ^{[1
]}

Sidorova, Elena N. ^{[1
]}

Vasiliev, Andrey A. ^{[1
]}

Ozherelkov, Dmitriy Yu. ^{[2
]}

Pelevin, Ivan A. ^{[2
]}

Gromov, Alexander A. ^{[2
]}

Nalivaiko, Anton Yu. ^{[2
]}

机构：

[1] Natl Univ Sci & Technol MISIS, Dept Funct Nanosyst & High Temp Mat, Moscow 119991, Russia

[2] Natl Univ Sci & Technol MISIS, Catalysis Lab, Moscow 119991, Russia

来源：

NANOMATERIALS | 2021年 / 11卷 / 09期

关键词：

XRF; matrix effect; absorption; nanoparticles; Cu; Ni; powder compositions; calibration curve; calibration measurement; CORROSION BEHAVIOR; SIZE; XRF; QUANTIFICATION; INTENSITY; SAMPLES; THIN;

D O I：

10.3390/nano11092388

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The study is devoted to X-ray fluorescence spectroscopy (XRF) features of micro- and nanosized powder mixtures of copper and nickel. XRF is a high accuracy method that allows for both qualitative and quantitative analysis. However, the XRF measurement error due to the size of the studied particles is not usually taken into account, which limits the use of the method in some cases, such as analysis of Ni-Cu mixtures and coatings. In this paper, a method for obtaining copper and nickel nanoparticles was investigated, and the XRF of powder compositions was considered in detail. The initial micro- and nanoparticles of copper and nickel were studied in detail using SEM, TEM, XRD, and EDX. Based on experimental data, calibration curves for copper-nickel powder compositions of various sizes were developed. According to the results, it was experimentally established that the calibration curves constructed for nanoscale and microscale powders differ significantly. The presented approach can be expanded for other metals and particle sizes.

引用

页数：15

共 50 条

[31] MEASUREMENT OF PARTICLE ABSORPTION BY X-RAY FLUORESCENCE
DEWOLFF, PM
ACTA CRYSTALLOGRAPHICA, 1956, 9 (07): : 682 - 683
[32] Comparing Compositions of Modern Cast Bronze Sculptures: Optical Emission Spectroscopy Versus x-Ray Fluorescence Spectroscopy
Young, M. L.
Dunand, D. C.
JOM, 2015, 67 (07) : 1646 - 1658
[33] Study of aggregate samples with iron sulfides through micro X-ray fluorescence (μXRF) and X-ray photoelectron spectroscopy (XPS)
S. Chinchón-Payá
A. Aguado
F. Coloma
S. Chinchón
Materials and Structures, 2015, 48 : 1285 - 1290
[34] X-RAY PHOTOELECTRON SPECTROSCOPY OF NICKEL COMPOUNDS
MATIENZO, LJ
YIN, LI
GRIM, SO
SWARTZ, WE
INORGANIC CHEMISTRY, 1973, 12 (12) : 2762 - 2769
[35] Study of aggregate samples with iron sulfides through micro X-ray fluorescence (μXRF) and X-ray photoelectron spectroscopy (XPS)
Chinchon-Paya, S.
Aguado, A.
Coloma, F.
Chinchon, S.
MATERIALS AND STRUCTURES, 2015, 48 (05) : 1285 - 1290
[36] Ni content of the US nickel coin determined by X-ray fluorescence and visible spectroscopy
Jagdeo, Sharda
Shin, Esther J.
Shin, Jun H.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
[37] X-RAY FLUORESCENCE SPECTROSCOPY IN CHEMICAL ANALYSIS
HALL, ET
ENDEAVOUR, 1959, 18 (70) : 83 - 87
[38] X-ray Fluorescence Spectroscopy of Novel Materials
E. Z. Kurmaev
Inorganic Materials, 2005, 41 : S1 - S23
[39] X-ray fluorescence spectroscopy for laboratory applications
Leopold, Kerstin
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2021, 413 (26) : 6455 - 6456
[40] ROCK ANALYSIS BY X-RAY FLUORESCENCE SPECTROSCOPY
CHODOS, AA
BRANCO, JJ
ENGEL, CG
SPECTROCHIMICA ACTA, 1958, 10 (03): : 337 - 337

← 1 2 3 4 5 →