Hierarchical three-dimensional Fe3O4@porous carbon matrix/graphene anodes for high performance lithium ion batteries

被引：61

作者：

Hao, Shiji ^{[1
]}

Zhang, Bowei ^{[2
]}

Wang, Ying ^{[2
]}

Li, Chaojiang ^{[2
]}

Feng, Jianyong ^{[2
]}

Ball, Sarah ^{[3
]}

Srinivasan, Madhavi ^{[1
,2
]}

Wu, Junsheng ^{[4
]}

Huang, Yizhong ^{[1
,2
]}

机构：

[1] Nanyang Technol Univ, Energy Res Inst NTU, Singapore 639798, Singapore

[2] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[3] Johnson Matthey Technol Ctr, Reading RG4 9NH, Berks, England

[4] Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Beijing 100083, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2018年 / 260卷

关键词：

Fe3O4; Porous carbon matrix; Graphene; Anode; Lithium ion batteries; METAL-ORGANIC FRAMEWORKS; GRAPHENE OXIDE; FE3O4; NANOPARTICLES; STORAGE CAPACITY; NANOCOMPOSITE; COMPOSITES; CO3O4; MICROSPHERES; FOAM; ELECTRODES;

D O I：

10.1016/j.electacta.2017.12.078

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In the present paper, the hierarchical three-dimensional Fe3O4@porous carbon matrix (PCM) and Fe3O4@PCM/graphene are synthesized by a facile annealing of Mil-53(Fe) templates. Their electrochemical performances are evaluated as anode materials for lithium ion batteries. In comparison with Fe3O4@PCM, the Fe3O4@PCM/graphene electrode exhibits a much better cycling performance with the reversible capacity high up to 1000 mAh g(-1) after 500 cycles at 1 C. The improved performance can be ascribed to the high conductivity and structure stability provided by the unique graphene based hierarchical three-dimensional nanostructure. (c) 2017 Elsevier Ltd. All rights reserved.

引用

页码：965 / 973

页数：9

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