Exciton in a phonon field: With a generalized dynamical coherent potential approximation (DCPA)

被引:0
|
作者
Kato, T [1 ]
Kobayashi, S [1 ]
机构
[1] Electrotech Lab, Tsukuba, Ibaraki 3058564, Japan
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中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A dynamical coherent potential approximation (DCPA) is formulated within the Hartree approximation for a Frenkel exciton interacting with intramolecular phonons. This method is applied to calculations of two-photon absorption spectra in molecular J-aggregates. The two-photon absorption map and the two-exciton polaron dispersion are compared for pseudoisocyanine J-aggregates. A possibility to observe band-edge lowest two-exciton polarons by the two-photon absorption spectroscopy is pointed out.
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页码:495 / 500
页数:6
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