Numerical analysis of solar-assisted seasonal 'open' thermochemical heat storage

In the last decade, interest in heat storage systems has been increasing. These systems will have increasing importance for utilization of solar energy in domestic heating systems. As solar energy is a diurnal cyclic resource, storing excess solar energy for long-or short-term periods will both increase the utilization of solar energy systems and decrease fossil fuel consumption. The relatively new heat storage method using thermochemical storage has shown some significant advantages such as low heat loss (-> zero), high heat storage density and low space requirement. These important properties make thermochemical storage a promising alternative for long-term energy storage. In the present study, a numerical investigation on 'open' seasonal thermochemical storage has been undertaken. The simulation results show that the volume/mass of the absorbent, mass flow rate and relative humidity of air have significant importance on the reaction kinetics and system performance during the system discharging process. Conversely, total collector area, solar radiation and mass flow rate of air are important parameters during the charging process. The results conclude that, overall, reactor design is the most important factor for storage performance. In addition, reaction advancement (X) has a significant importance on process efficiency.