Carbon Nanosheet Anode for Sodium-Ion Storage and Its Application in Sodium-Ion Hybrid Capacitors

被引：6

作者：

Chen, Li ^{[1
]}

Duan, Wenhui ^{[1
,2
]}

Yang, Bingjun ^{[2
]}

Liu, Bao ^{[2
]}

Li, Hongxia ^{[1
]}

Lang, Junwei ^{[2
]}

Chen, Jiangtao ^{[2
]}

机构：

[1] Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China

[2] Chinese Acad Sci, Lab Clean Energy Chem & Mat, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China

来源：

CHEMISTRYSELECT | 2020年 / 5卷 / 19期

基金：

中国国家自然科学基金;

关键词：

carbon nanosheet; hybrid capacitor; high power density; sodium-ion battery; GRAPHENE; BATTERIES; CHALLENGES; TEMPLATES; ELECTRODE;

D O I：

10.1002/slct.202001696

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, sodium ion hybrid capacitors (SIHCs) constructed by using battery-type carbon nanosheet (CNS) as anode and capacitive activated carbon (AC) as cathode are reported. The CNSs with large interlayer spacing were deposited on Na2CO3 powder by using chemical vapor deposition method. The CNS anode for sodium ion storage exhibits outstanding rate capability (138 mAh g(-1) at 10 A g(-1), 63 % retention of the capacity at 0.05 A g(-1)) and excellent long-term cyclability at 10 A g(-1) after 12500 cycles. Benifting from high performance of anodes abovemensioned, the assembled SIHC based on CNS and AC, operated in a voltage window of 1.0 similar to 4.0 V, delivers a high specific energy of 135 Wh kg(-1) at 250 W kg(-1) and a maximum power of 25 kW kg(-1) with the output 69 Wh kg(-1).

引用

页码：5824 / 5830

页数：7

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