Pyrolysis of n-heptane: Kinetics and modeling

被引：59
|
作者：
Pant, KK [1 ]
Kunzru, D [1 ]
机构：
[1] INDIAN INST TECHNOL,DEPT CHEM ENGN,KANPUR 208016,UTTAR PRADESH,INDIA
来源：
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 1996年 / 36卷 / 02期
关键词：
kinetics; product distribution; n-heptane; molecular reaction scheme; pyrolysis;
D O I：
10.1016/0165-2370(95)00925-6
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The kinetics and product distribution during the pyrolysis of n-heptane have been investigated in the temperature range 953-1023 K at atmospheric pressure, with steam as the inert diluent. The overall n-heptane decomposition can be represented by a first-order reaction with a frequency factor of 6.02 x 10(13) s(-1) and an activation energy of 250.7 kJ mol(-1). The experimental product yields could be satisfactorily modeled by use of a molecular reaction scheme, consisting of a first-order primary reaction and 24 secondary reactions among the primary products.
引用
收藏
页码：103 / 120
页数：18
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