Endo-endo mode intramolecular reductive cyclization of cyclic 1,2-bis(silylethynyl)benzenes

被引：9
|
作者：
Yamaguchi, S [1 ]
Miyasato, M
Tamao, K
机构：
[1] Kyoto Univ, Chem Res Inst, Kyoto 6110011, Japan
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan
[3] JST, PRESTO, Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
CHEMISTRY LETTERS | 2003年 / 32卷 / 12期
关键词：
D O I：
10.1246/cl.2003.1104
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Upon treatment of cyclic 1,2-bis(silylethynyl)benzenes with lithium naphthalenide, the intramolecular reductive cyclization proceeds in an endo-endo mode to produce 1,4-dilithio-2,3-disilylnaphthalenes, which are transformed into a series of 1,4-di-functionalized 2,3-disilylnaphthalenes.
引用
收藏
页码：1104 / 1105
页数：2
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