Design a flower-like magnetic graphite carbon microsphere for enhanced adsorption of 2,4-dichlorophenol

被引:3
|
作者
Li, Zhaoyang [1 ,2 ]
Mao, Yanli [1 ,2 ]
Yan, Xiaole [1 ]
Song, Zhongxian [1 ]
Liu, Chaopeng [3 ]
Liu, Zuwen [2 ]
Kang, Haiyan [1 ]
Yan, Xu [1 ]
Gu, Deming [1 ]
Zhang, Xia [1 ]
Huang, Zhenzhen [1 ,4 ]
机构
[1] Henan Univ Urban Construct, Henan Key Lab Water Pollut Control & Rehabil Tech, Pingdingshan 467000, Peoples R China
[2] Jiangxi Univ Sci & Technol, Sch Civil & Surveying Engn, Ganzhou 341000, Peoples R China
[3] North China Univ Water Resources & Elect Power, Sch Environm & Municipal Engn, Zhengzhou 450046, Peoples R China
[4] Zhengzhou Univ, Sch Water Conservancy & Engn, Zhengzhou 450001, Peoples R China
基金
中国国家自然科学基金;
关键词
Activated carbon; Nanoparticles; Structural design; Adsorption; AQUEOUS-SOLUTIONS; ACTIVATED CARBON; CONGO RED; REMOVAL; KINETICS; COMPOSITE; LEAD; CARBONIZATION; NANOCOMPOSITE; DEGRADATION;
D O I
10.1007/s11356-022-21364-x
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
2,4-Dichlorophenol (2,4-DCP) is a hazardous chlorinated organic chemical, so its removal is an important task to protect the whole ecosystem and human health. During the material preparation, the magnetic graphitic carbon adsorbent (HFMCM) with a sparse sheet-like stacking structure was formed by interlayer assembly of nickel hydroxide nanosheets and hydrothermal glucose carbon. The conditions for optimal performance of the adsorbent are 45 degrees C and pH 5. The maximum adsorption capacity of HFMCM-180 for 2,4-DCP is 147.06 mg.g(-1). Adsorption behavior in accordance with Langmuir isothermal model and pseudo-second-order kinetic models. The adsorbent remains selective for 2,4-DCP in metal ion solutions. More than 75% of the adsorption capacity is maintained after five cycles of adsorption. Electrostatic interaction, hydrogen bonding, and pi-pi bonding play a major role in the adsorption of 2,4-DCP by HFMCM.
引用
收藏
页码:83138 / 83154
页数:17
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