STRUCTURAL FEATURES OF CADMIUM(II) COMPLEXES WITH BIS(BENZIMIDAZOL-2-YL)METHANE

被引：3
|
作者：
Smirnova, K. S. [1 ]
Sukhikh, T. S. [1 ,2 ]
Adonin, S. A. [1 ]
El'tsov, I., V [2 ]
Lider, E., V [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 62卷 / 05期
关键词：
cadmium; benzimidazole; mononuclear complexes; cationic-anionic compounds; crystal structure; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; FLUORESCENT PROPERTIES; LIGANDS; COBALT(II); DIVERSITY;
D O I：
10.1134/S0022476621050085
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of cadmium(II) coordination compounds with bis(benzimidazol-2-yl)methane (L) is synthesized. Single crystals are obtained, and molecular and crystal structures of [Cd-4(L)(4)Cl-6(EtOH)(0.77)(H2O)(1.23)] [CdCl4]center dot H2O center dot 5EtOH, [Cd(L)I-2], and [Cd(L)(2)(EtOH)(2)][Cd(L)(NO3)(3)](2)center dot 6EtOH complexes are determined. According to the single crystal X-ray diffraction analysis, the organic ligand has a bidentate cyclic coordination. Distinctions in the structures of the compounds depending on the anion present are observed. The [Cd(L)I-2] complex is mononuclear with cadmium ions are in the tetrahedral environment. Cadmium chloride and nitrate complexes are cationic-anionic with cadmium ions in different environments, and their coordination numbers vary in the range of 4-7.
引用
收藏
页码：718 / 726
页数：9
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