Transition metal-catalyzed decarboxylative cross-coupling reactions

被引：426

作者：

Shang Rui ^{[1
]}

Liu Lei ^{[1
,2
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2011年 / 54卷 / 11期

关键词：

decarboxylation; cross-coupling reaction; transition metal; catalysis; organic synthesis; CARBOXYLIC-ACIDS; BIARYL SYNTHESIS; BENZOIC-ACIDS; ARENECARBOXYLIC ACIDS; ARYL HALIDES; C-H; AROMATIC CARBOXYLATES; VERSATILE CATALYST; DIRECT ARYLATION; OLEFINATION;

D O I：

10.1007/s11426-011-4381-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal-catalyzed decarboxylative cross-coupling reactions have recently emerged as a new and important category of organic transformations that find versatile applications in the construction of carbon-carbon and carbon-heteroatom bonds. The use of relatively cheap and stable carboxylic acids to replace organometallic reagents enables the decarboxylative cross-coupling reactions to proceed with good selectivities and functional group tolerance. In the present review we summarize the various types of decarboxylative cross-coupling reactions catalyzed by different transition metal complexes. The scope and applications of these reactions are described. The challenges and opportunities in the field are discussed.

引用

页码：1670 / 1687

页数：18

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