209Bi NQR study of bismuth(III) complexes

被引：4
|
作者：
Zemnukhova, LA
Kuznetsov, SI
Davidovich, RL
机构：
[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 11期
关键词：
Bi-209 NQR spectra; bismuth(III); complexes; complexonates; potassium pentafluorobismuthate(III); nitrate-chloride and sulfate-chloride bismuth(III) compounds;
D O I：
10.1007/BF02494274
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Potassium pentafluorobismuthate(III), nitrate-chloride Bi-III complexes MBiCl3NO3 (M = K, (NH2)(2)CNH2), sulfate-chloride Bi-III complexes MBiCl2SO4 (M = K, Rb, NH4, (NH2)(2)CNH2), and Bi-III complexonates with the anions of ethylenediaminetetraacetic acid M[Bi(edta)](2). nH(2)O (M = Mg, Ca, Ni, Cd) and nitrilotriacetic acid Bi(nta). 2H(2)O, and Bi(nta). 3thio . H2O (thio is thiourea) were studied by Bi-209 NQR spectroscopy. A second-order phase transition was observed in K2BiF5 at 100 K. The compounds Bi(nta). 2H(2)O, (NH2)(2)CNH2BiCl3NO3, and MBiCl2SO4 (M = K, NH4) are piezoelectrics.
引用
收藏
页码：2169 / 2172
页数：4
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