Palladium-Catalyzed Oxidative Cross-Coupling Reaction of Arylboronic Acids with Diazoesters for Stereoselective Synthesis of (E)-α,β-Diarylacrylates

被引：70

作者：

Tsoi, Yuk-Tai

Zhou, Zhongyuan

Chan, Albert S. C.

Yu, Wing-Yiu ^{[1
]}

机构：

[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, State Key Lab Chiosci, Kowloon, Hong Kong, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 20期

关键词：

ALPHA-DIAZOCARBONYL COMPOUNDS; CARBENE INSERTION; BIOLOGICAL EVALUATION; ARYLATION;

D O I：

10.1021/ol101796t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Pd-catalyzed oxidative cross-coupling reaction of arylboronic acids with alpha-diazoesters was achieved using molecular oxygen as the sole reoxidant, and E-alpha,beta-diarylacrylates were obtained in good yields and >20 1 E-to-Z selectivity

引用

页码：4506 / 4509

页数：4

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