Tandem asymmetric conjugate addition-enolacetates formation of enantiomerically enriched zinc and aluminium enolates

被引：27
|
作者：
Vuagnoux-d'Augustin, Magall [1 ]
Alexakis, Alexandre [1 ]
机构：
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 41期
关键词：
D O I：
10.1016/j.tetlet.2007.07.220
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The metal enolates, resulting from the copper-catalyzed enantio selective conjugate addition of organometallic reagents (Et2Zn or R3Al) to cyclic and acyclic enones are quantitatively trapped as enolacetates with acetic anhydride. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7408 / 7412
页数：5
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