Solvent extraction and spectrophotometric determination of Fe(II) with 1,3-diphenyl-4-carboethoxy pyrazole-5-one

被引：0

作者：

Patil, RK ^{[1
]}

Dhuley, DG ^{[1
]}

机构：

[1] Marathwada Univ, Dept Chem, Aurangabad 431004, Maharashtra, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2000年 / 39卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A quick and selective method is developed for extractive spectrophotometric determination of Fe(II) using 1,3-diphenyl-4-carboethoxy pyrazole-5-one as the reagent. The wine-red coloured 1:3 (metal:ligand) complex in chloroform medium absorbs maximally at 525 nm. Beer's law is obeyed in the concentration range 0.5 - 10 mug/ml of Fe(II). The molar absorptivity and Sandell's sensitivity are found to be 1.156x10(3)l mol(-1) cm(-1) and 0.0483 mu gcm(-2) respectively. The effect of pH. equilibration time, reagent concentration and foreign ions have also been studied. The application of the method has been applied for the determination of Fe(II) in pharmaceutical samples.

引用

页码：1105 / 1106

页数：2

共 50 条

[21] A Theoretical Study on the Photochromic Mechanism of 1-Phenyl-3-methyl-4-(6-hydro-4-amino-5-sulfo-2,3-pyrazine)-pyrazole-5-one
Liu An-Jie
Jia Dian-Zeng
Wu Dong-Ling
Liu Lang
Guo Ji-Xi
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (06) : 821 - 829
[22] A Theoretical Study on the Photochromic Mechanism of 1-Phenyl-3-methyl-4-(6-hydro-4-amino-5-sulfo-2,3-pyrazine)-pyrazole-5-one
刘岸杰
贾殿赠
吴冬玲
刘浪
郭继玺
结构化学, 2014, 33 (06) : 821 - 829
[23] EXTRACTION AND SPECTROPHOTOMETRIC DETERMINATION OF PD(II) WITH 2'-HYDROXY-4-METHOXY-5'-METHYLCHALKONE OXIME
DESHMUKH, BK
KHARAT, RB
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1976, 14 (03): : 214 - 215
[24] SOLVENT EXTRACTION-SPECTROPHOTOMETRIC DETERMINATION OF NICKEL(II) WITH 2,2'-DIPYRIDYLGLYOXALBIS (4,4-DIPHENYLSEMICARBAZONE)
KATO, T
HAMADA, M
INOSHITA, H
BUNSEKI KAGAKU, 1985, 34 (03) : 124 - 128
[25] STUDIES ON THE EXTRACTION AND SPECTROPHOTOMETRIC DETERMINATION OF NI(II), FE(II), FE(III) AND V(IV) WITH BIS(4-HYDROXYPENT-2-YLIDENE)DIAMINOETHANE
NWABUE, FI
OKAFO, EN
TALANTA, 1992, 39 (03) : 273 - 280
[26] INDIRECT EXTRACTION-SPECTROPHOTOMETRIC METHOD FOR THE DETERMINATION OF TRACES OF TIN(II) BY MEANS OF 4,7-DIPHENYL-1,10-PHENANTHROLINE
GREGOROWICZ, Z
BAKOWSKI, W
ANALYTICA CHIMICA ACTA, 1979, 104 (02) : 363 - 368
[27] Synthesis, crystal structure and photochromism properties of 1-phenyl-3-methyl-4-(6-hydro-4-amino-5-sulfo-2,3-pyrazine)-pyrazole-5-one
Liu, L
Jia, DZ
Yu, KB
ACTA CHIMICA SINICA, 2002, 60 (03) : 493 - 498
[28] ISONITROSO-4-METHYL-2-PENTANONE FOR SOLVENT-EXTRACTION AND SPECTROPHOTOMETRIC DETERMINATION OF PALLADIUM(II) AT TRACE-LEVEL
MORE, PS
SAWANT, AD
ANALYTICAL LETTERS, 1994, 27 (09) : 1737 - 1748
[29] EXTRACTION-SPECTROPHOTOMETRIC DETERMINATION OF PD(II) WITH 4-(3,5-DICHLORO-2-PYRIDYLAZO)-1,3-DIAMINOBENZENE AND TRICHLOROACETATE .1.
FONTAN, CA
MARONE, CB
OLSINA, R
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (11) : 4113 - 4119
[30] SOLVENT-EXTRACTION AND SPECTROPHOTOMETRIC DETERMINATION OF GALLIUM(III) WITH SODIUM 2-BROMO-4,5-DIHYDROXYAZOBENZENE-4'-SULFONATE IN THE PRESENCE OF 1,3-DIPHENYLGUANIDINIUM
WAKAMATSU, Y
BUNSEKI KAGAKU, 1979, 28 (06) : 385 - 388

← 1 2 3 4 5 →