Carbon nanospheres derived from sunflower seed husk composited with anatase TiO2 used as anode for lithium-ion battery

被引:1
|
作者
Li, Xiangji [1 ,2 ]
Wang, Xinyan [1 ,2 ]
Xu, Xi [3 ]
Yu, Kaifeng [1 ]
Liang, Ce [1 ]
机构
[1] Jilin Univ, Coll Mat Sci & Engn, Key Lab Automobile Mat, Minist Educ, Changchun 130025, Peoples R China
[2] Jilin Univ, Roll Forging Res Inst, Changchun 130025, Jilin, Peoples R China
[3] Hosp 964 Chinese Peoples Liberat Army Joint Suppo, Orthodont Dept, Changchun 130000, Peoples R China
基金
中国博士后科学基金;
关键词
Lithium-ion battery; Carbon nanospheres; Sunflower seed husk; Anatase TiO2; Composite; REDUCED GRAPHENE OXIDE; HIGH-RATE PERFORMANCE; HOLLOW SPHERES; POROUS CARBON; DOPED CARBON; NANOSHEETS; NANOPARTICLES; NANOMATERIALS; FABRICATION; STORAGE;
D O I
10.1007/s11581-021-04402-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, the sunflower seed husks were chosen as raw material to prepare carbon matrix. The ammonium persulfate ((NH4)(2)S2O8) was used as catalyst to obtain the biomass-derived carbon and anatase TiO2 composite. To explore the influence of different crystal TiO2 on the composite material, the carbon mix with P25 TiO2 was prepare to contrast. The size and distribution of the titanium dioxide in nanosphere activated carbon and anatase TiO2 composite named NAC@TiO2-A are both uniform. And the structure of prepared material is crosslinked spherically, of which specific surface area is 365.31 m(2) g(-1) and average pore diameter is 3.65 nm. When using NAC@TiO2-A as the anode of lithium-ion battery, after 100 cycles at 0.2C, the discharge specific capacity held steady at 895.3 mA h g(-1). And it also delivered a high capacity of 513.6 mA h g(-1) at 2C and 379.3 mA h g(-1) at 5C after 100 cycles.
引用
收藏
页码:1635 / 1646
页数:12
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