Structural and spectral studies of a new copper(II) complex with a tridentate thiosemicarbazone ligand

被引：17
|
作者：
Sen, Soma [1 ]
Shit, Shyamapada [1 ]
Mitra, Samiran [1 ]
Batten, Stuart R. [2 ]
机构：
[1] Univ Jadavpur, Dept Chem, Kolkata 700032, W Bengal, India
[2] Monash Univ, Dept Chem, Clayton, Vic, Australia
来源：
STRUCTURAL CHEMISTRY | 2008年 / 19卷 / 01期
关键词：
Cu(II); thiosemicarbazone ligand; X-ray structure; spectroscopic; electrochemical; thermal analysis;
D O I：
10.1007/s11224-007-9263-x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of copper(II) chloride dihydrate with 2-hydroxy-3-methoxybenzaldehydethiosemicarbazone (HL) ligand in a 1: 1 ratio forms the complex [Cu(L)(Cl)] center dot H2O. The complex is characterized by spectroscopic, electrochemical, and thermal analysis. X-ray crystallographic analysis reveals that the central copper atom displays the distorted square planar geometry. The water molecule present in the lattice participates in a strong hydrogen bonding network, which leads to a 2D supramolecular arrangement.
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页码：137 / 142
页数：6
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