Synthesis, characterization, electrochemistry and evaluation of biological activities of some ferrocenyl Schiff bases

被引：52

作者：

Zaheer, Muhammad ^{[1
]}

Shah, Afzal ^{[1
]}

Akhter, Zareen ^{[1
]}

Qureshi, Rumana ^{[1
]}

Mirza, Bushra ^{[2
]}

Tauseef, Misbah ^{[2
]}

Bolte, Michael ^{[3
]}

机构：

[1] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan

[2] Quaid I Azam Univ, Dept Biochem, Islamabad 45320, Pakistan

[3] Goethe Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2011年 / 25卷 / 01期

关键词：

ferrocene; Schiff bases; electrochemistry; biological applications; DERIVATIVES; ABSORPTION; REDUCTION; CHEMISTRY; ANALOGS; COMPLEX; DNA;

D O I：

10.1002/aoc.1690

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Synthesis of ferrocenyl Schiff bases (1-6) was carried out by the condensation reaction of 4-ferrocenyl aniline with different substituted aromatic aldehydes and acetyl acetone. Compounds were characterized by physical measurements, elemental analysis, FT-IR, H-1-NMR and C-13-NMR spectroscopy. Single crystal X-ray analysis of compound 2 showed the co-planarity of both aromatic rings connected by a C-N double bond. Compounds demonstrated reversible one-electron redox behavior and their peak currents were found to increase linearly with the square root of the sweep rate nu(1/2). The overall electrode processes were found to be diffusion controlled. Compounds 1 and 4 showed low cytotoxicity and appreciable antifungal, antioxidant and DNA protection activities. Copyright (C) 2010 John Wiley & Sons, Ltd.

引用

页码：61 / 69

页数：9

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