C(sp3) -H Bond Functionalization Mediated by Hydride a Shift/Cyclization System

被引：24
|
作者：
Mori, Keiji [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Dept Appl Chem, 2-24-16 Nakacho, Koganei, Tokyo 1848588, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2022年 / 95卷 / 02期
基金：
日本学术振兴会;
关键词：
C(sp(3))-H bond functionalization; Hydride shift; Redox process; RING-CLOSURE REACTIONS; BRONSTED ACID; ASYMMETRIC-SYNTHESIS; 1,5-HYDRIDE TRANSFER/CYCLIZATION; STEREOCHEMICAL ASPECTS; HETEROCYCLIC SYNTHESIS; EXPEDITIOUS SYNTHESIS; ALKYLATION REACTIONS; ALPHA-CYCLIZATION; TERTIARY-AMINES;
D O I：
10.1246/bcsj.20210420
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient catalytic internal redox reaction (hydride shift mediated C(sp(3))-H bond functionalization) has been developed, which has the following salient features: (1) C(sp(3))-H bond functionalization, (2) Lewis and/or Bronsted acid catalyzed reaction (transition metals employed in conventional CH bond functionalization are not required), and (3) construction of complex polycycles that are otherwise difficult to synthesize by conventional methods. Our recent efforts on the development of novel types of C(sp(3))-H bond functionalization mediated by the hydride shift/cyclization system are described.
引用
收藏
页码：296 / 305
页数：10
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