Electrochemistry of Zirconium Tetrachloride in the Ionic Liquid N-Butyl-N-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide: Formation of Zr(III) and Exploitation of ZrCl4 as a Facile Ionic Liquid Drying Agent

被引：5

作者：

Fu, Chaopeng ^{[1
,2
]}

Aldous, Leigh ^{[1
]}

Manan, Ninie S. A. ^{[3
,4
]}

Compton, Richard G. ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China

[3] Queens Univ Belfast, QUILL Ctr, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland

[4] Univ Malaya, Fac Sci, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

ELECTROANALYSIS | 2012年 / 24卷 / 02期

关键词：

Zirconium tetrachloride; Electrochemistry; Room temperature ionic liquid; Drying agent; ELECTRODES; DIFFUSION; SOLVENTS;

D O I：

10.1002/elan.201100513

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrochemistry of zirconium tetrachloride in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide has been studied, and the one electron reduction is proved by chronoamperometry. Furthermore, we report the application of ZrCl4 as a facile and general ionic liquid drying agent for use in voltammetry.

引用

页码：210 / 213

页数：4

共 37 条

[31] Electrodeposition of Ni, Fe and Ni-Fe Alloys in Two Ionic Liquids: (tri (n-butyl) [2-methoxy-2-oxoethyl] Ammonium bis (trifluoromethylsulfonyl) [BuGBOEt] [Tf2N] and (1-butyl-1-methylpyrrolidinium bis trifluoromethylsulfonyl) imide ([P1,4] [Tf2N])
Maizi, Rafik
Fricoteaux, Patrick
Mohamadou, Aminou
Meddour, Athmane
Rousse, Celine
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2016, 11 (08): : 7111 - 7124
[32] Molecular Simulation Study of the Solubility, Diffusivity and Permselectivity of Pure and Binary Mixtures of CO2 and CH4 in the Ionic Liquid 1-n-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
Budhathoki, Samir
Shah, Jindal K.
Maginn, Edward J.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2015, 54 (35) : 8821 - 8828
[33] Aqueous N-H acid bis(trifluoromethylsulfonyl) imide Solution - [C4mim] [Tf2N] Ionic Liquid Biphasic System: an Original Investigation by Diffusion Ordered Spectroscopy Nuclear Magnetic Resonance
Mazan, Valerie
Boltoeva, Maria
JOURNAL OF FLUORINE CHEMISTRY, 2021, 245
[34] Exploring the effect of novel N-butyl-6-methylquinolinium bis (trifluoromethylsulfonyl)imide ionic liquid addition to poly(methyl methacrylate-co-methacrylic) acid electrolyte system as employed in gel-state dye sensitized solar cells
Sundararajan, V.
Selvaraj, G.
Ng, H. M.
Ramesh, S.
Ramesh, K.
Wilfred, C. D.
Bashir, Shahid
ELECTROCHIMICA ACTA, 2017, 240 : 361 - 370
[35] The structure of [Co(H-tptz)Cl3] • H2O (tptz=2,4,6-tri(2-pyridyl)-1,3,5-triazine) prepared by crystallization from the ionic liquid, N-butyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide
Holbrey, John D.
Vigour, Kate B.
Reichert, W. Matthew
Rogers, Robin D.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2006, 36 (12) : 799 - 804
[36] The structure of [Co(H-tptz)Cl3]·H2O (tptz=2,4,6-tri(2-pyridyl)-1,3,5-triazine) prepared by crystallization from the ionic liquid, N-butyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide
John D. Holbrey
Kate B. Vigour
W. Matthew Reichert
Robin D. Rogers
Journal of Chemical Crystallography, 2006, 36 : 799 - 804
[37] Reactivity Towards Europium(III) of the Radiolysis Products of the Ionic Liquid 1-Methyl-3-butyl-1H-imidazolium Bis[(trifluoromethyl)sulfonyl]amide (C4-mimTf2N) and Effect of Water: A TRLFS (Time-Resolved Laser-Induced Fluorescence Spectroscopy) Preliminary Study
Billard, Isabelle
Georg, Sylvia
HELVETICA CHIMICA ACTA, 2009, 92 (11) : 2227 - 2237

← 1 2 3 4 →