Electrochemistry of Zirconium Tetrachloride in the Ionic Liquid N-Butyl-N-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide: Formation of Zr(III) and Exploitation of ZrCl4 as a Facile Ionic Liquid Drying Agent

被引：5
|
作者：
Fu, Chaopeng [1 ,2 ]
Aldous, Leigh [1 ]
Manan, Ninie S. A. [3 ,4 ]
Compton, Richard G. [1 ]
机构：
[1] Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
[2] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
[3] Queens Univ Belfast, QUILL Ctr, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland
[4] Univ Malaya, Fac Sci, Dept Chem, Kuala Lumpur 50603, Malaysia
来源：
ELECTROANALYSIS | 2012年 / 24卷 / 02期
关键词：
Zirconium tetrachloride; Electrochemistry; Room temperature ionic liquid; Drying agent; ELECTRODES; DIFFUSION; SOLVENTS;
D O I：
10.1002/elan.201100513
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The electrochemistry of zirconium tetrachloride in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide has been studied, and the one electron reduction is proved by chronoamperometry. Furthermore, we report the application of ZrCl4 as a facile and general ionic liquid drying agent for use in voltammetry.
引用
收藏
页码：210 / 213
页数：4
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