Electron Diffraction Study of the Structure of Titanium, Zirconium, and Hafnium Tetranitrates in the Gas Phase

被引:0
|
作者
Lapshina, S. B. [1 ]
Girichev, G. V. [1 ]
Pilipets, O. V. [2 ]
Ermolaeva, L. I. [2 ]
Spiridonov, V. P. [2 ]
Golubinskii, A. V. [2 ]
机构
[1] Ivanovo State Acad Chem Technol, Ivanovo, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119899, Russia
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The molecular structures of titanium, zirconium, and hafnium tetranitrates in the gas phase were studied by electron diffraction. It was found that the model of D(4) symmetry with NO(3) fragments bound to the central metal atom via two bridging oxygen atoms provides the best agreement with the experimental data.
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页码:1176 / 1178
页数:3
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